A numerical model for design of the geomembrane elements of waste containment systems has been validated by laboratory testing. Due to the absence of any instrumented case histories of seismic performance of geomembrane liner systems, a large scale centrifuge test of a model geomembrane-lined landfill subject to seismic loading was conducted at the University of California at Davis Centrifuge Test facility as part of National Science Foundation Network for Earthquake the Engineering Simulation Research (NEESR) program. Data collected in the large scale centrifuge test included waste settlement, liner strains and earthquake accelerations at various locations throughout the model. This data on landfill and liner seismic performance has been supplemented with additional laboratory and small scale centrifuge tests to determine the parameters required for the numerical model, including strength and stiffness of the model materials, interface shear strengths, and interface stiffness. The numerical model explicitly assesses the forces and strains in the geomembrane elements of a containment system to subject to both static and seismic loads the computer code FLACTM, a finite difference program for non-linear analysis of continua. The model employs a beam element with zero moment of inertia and with interface elements on both sides to model to represent the geomembrane elements in the liner system. The model also includes non-linear constitutive models for the stress-strain behavior of geomembrane beam elements and an elastic-perfectly plastic model for the load-displacement behavior of the beam interfaces. Parametric studies are conducted with the validated numerical model to develop recommendations for landfill design, construction, and construction quality assurance.

Concern and interest about the environment and ecologic systems have promoted the usage of earth as a construction material. Technology advancement has resulted in the evolution of adobe into compressed stabilized earth blocks (CSEB). CSEB’s are prepared by compressing the soil-stabilizer mixture at a particular stress. In order to accomplish the required strength, cement has been used in a regular basis as stabilizing agent. It is of interest to find means to reduce the cement used in their construction without affecting its dry strength and durability. In this study, natural fibers were used along with lower proportions of cement to stabilize soil with varying fine content. Blocks were compacted at 10MPa stress and prepared by using 7%, 5% and 3% cement along with fiber content ranging from 0.25% to 2%. The effect of fine content, cement and fibers on strength and durability of the CSEB blocks were studied. Different sand/fine fractions of a native Arizona soil were used to fabricate the blocks. Results indicate that the compressive strength reaches a maximum value for blocks with 30% fine content and inclusion of fibers up to 0.5% increased the dry compressive strength. The use of 0.25% fiber by weight and 5% cement content showed comparable dry compressive strength to that of the 7% cement blocks with no fibers. The dry strength of the blocks reached an optimal condition when the combination of materials was 30% fines, 5% cement and 0.5% fibers, which satisfied the strength requirement given by the ASTM C62 and ASTM C216 standards for construction material. The CSEB’s with 0.5% fiber had higher toughness. The durability was determined by subjecting the CSEBs to wetting and drying cycles. The blocks with 5% cement withstand the durability test as the dry strength was higher than that required for construction use.

The blocks were also submitted to heating and cooling cycles. After 12 cycles, the specimens showed a reduction in strength, which further increased as the number of cycles increased. Finally, the thermal resistivity of fiber reinforced CSEB was found to be higher than that for clay bricks.

Nanotechnology has been applied to many areas such as medicine, manufacturing, catalysis, food, cosmetics, and energy since the beginning 21st century. However, the application of nanotechnology to geotechnical engineering has not received much attention. This research explored the technical benefits and the feasibility of applying nanoparticles in geotechnical engineering. Specific studies were conducted by utilizing high-pressure devices, axisymmetric drop shape analysis (ADSA), microfluidics, time-lapse technology, Atomic Force Microscopy (AFM) to develop experiments. The effects of nanoparticle on modifying interfacial tension, wettability, viscosity, sweep efficiency and surface attraction forces were investigated. The results show that nanoparticles mixed in water can significantly reduce the interfacial tension of water in CO2 in the applications of nanofluid-CO2 flow in sediments; nanoparticle stabilized foam can be applied to isolate contaminants from clean soils in groundwater/soil remediation, as well as in CO2 geological sequestration or enhanced oil/gas recovery to dramatically improve the sweep efficiency; nanoparticle coatings are capable to increase the surface adhesion force so as to capture migrating fine particles to help prevent clogging near wellbore or in granular filter in the applications of oil and gas recovery, geological CO2 sequestration, geothermal recovery, contaminant transport, groundwater flow, and stormwater management system.

A series of experiments were conducted to support validation of a numerical model for the performance of geomembrane liners subject to waste settlement and seismic loading. These experiments included large scale centrifuge model testing of a geomembrane-lined landfill, small scale laboratory testing to get the relevant properties of the materials used in the large scale centrifuge model, and tensile tests on seamed geomembrane coupons. The landfill model in the large scale centrifuge test was built with a cemented sand base, a thin film NafionTM geomembrane liner, and a mixture of sand and peat for model waste. The centrifuge model was spun up to 60 g, allowed to settle, and then subjected to seismic loading at three different peak ground accelerations (PGA). Strain on the liner and settlement of the waste during model spin-up and subsequent seismic loading and accelerations throughout the model due to seismic loading were acquired from sensors within the model. Laboratory testing conducted to evaluate the properties of the materials used in the model included triaxial compression tests on the cemented sand base, wide-width tensile testing of the thin film geomembrane, interface shear testing between the thin film geomembrane and the waste material, and one dimensional compression and cyclic direct simple shear testing of the sand-peat mixture used to simulate the waste. The tensile tests on seamed high-density polyethylene (HDPE) coupons were conducted to evaluate strain concentration associated with seams oriented perpendicular to an applied tensile load. Digital image correlation (DIC) was employed to evaluate the strain field, and hence seam strain concentrations, in these tensile tests. One-dimensional compression tests were also conducted on composite sand and HDPE samples to evaluate the compressive modulus of HDPE. The large scale centrifuge model and small scale laboratory tests provide the necessary data for numerical model validation. The tensile tests on seamed HDPE specimens show that maximum tensile strain due to strain concentrations at a seam is greater than previously suggested, a finding with profound implications for landfill liner design and construction quality control/quality assurance (QC/QA) practices. The results of the one-dimensional compression tests on composite sand-HDPE specimens were inconclusive.

The understanding of multiphase fluid flow in porous media is of great importance in many fields such as enhanced oil recovery, hydrology, CO2 sequestration, contaminants cleanup, and natural gas production from hydrate bearing sediments.

In this study, first, the water retention curve (WRC) and relative permeability in hydrate bearing sediments are explored to obtain fitting parameters for semi-empirical equations. Second, immiscible fluid invasion into porous media is investigated to identify fluid displacement pattern and displacement efficiency that are affected by pore size distribution and connectivity. Finally, fluid flow through granular media is studied to obtain fluid-particle interaction. This study utilizes the combined techniques of discrete element method simulation, micro-focus X-ray computed tomography (CT), pore-network model simulation algorithms for gas invasion, gas expansion, and relative permeability calculation, transparent micromodels, and water retention curve measurement equipment modified for hydrate-bearing sediments. In addition, a photoelastic disk set-up is fabricated and the image processing technique to correlate the force chain to the applied contact forces is developed.

The results show that the gas entry pressure and the capillary pressure increase with increasing hydrate saturation. Fitting parameters are suggested for different hydrate saturation conditions and morphologies. And, a new model for immiscible fluid invasion and displacement is suggested in which the boundaries of displacement patterns depend on the pore size distribution and connectivity. Finally, the fluid-particle interaction study shows that the fluid flow increases the contact forces between photoelastic disks in parallel direction with the fluid flow.

The dissimilatory reduction of nitrate, or denitrification, offers the potential of a sustainable, cost effective method for the non-disruptive mitigation of earthquake-induced soil liquefaction. Worldwide, trillions of dollars of infrastructure are at risk for liquefaction damage in earthquake prone regions. However, most techniques for remediating liquefiable soils are either not applicable to sites near existing infrastructure, or are prohibitively expensive. Recently, laboratory studies have shown the potential for biogeotechnical soil improvement techniques such as microbially induced carbonate precipitation (MICP) to mitigate liquefaction potential in a non-disruptive manner. Multiple microbial processes have been identified for MICP, but only two have been extensively studied. Ureolysis, the most commonly studied process for MICP, has been shown to quickly and efficiently induce carbonate precipitation on particle surfaces and at particle contacts to improve the stiffness, strength, and dilatant behavior of liquefiable soils. However, ureolysis also produces copious amounts of ammonium, a potentially toxic byproduct. The second process studied for MICP, denitrification, has been shown to precipitate carbonate, and hence improve soil properties, much more slowly than ureolysis. However, the byproducts of denitrification, nitrogen and carbon dioxide gas, are non-toxic, and present the added benefit of rapidly desaturating the treated soil. Small amounts of desaturation have been shown to increase the cyclic resistance, and hence the liquefaction resistance, of liquefiable soils. So, denitrification offers the potential to mitigate liquefaction as a two-stage process, with desaturation providing short term mitigation, and MICP providing long term liquefaction resistance. This study presents the results of soil testing, stoichiometric modeling, and microbial ecology characterization to better characterize the potential use of denitrification as a two-stage process for liquefaction mitigation.

Up to 25 percent of the operating budget for contaminated site restoration projects is spent on site characterization, including long-term monitoring of contaminant concentrations. The sensitivity, selectivity, and reproducibility of analytical methods have improved to the point where sampling techniques bear the primary responsibility for the accuracy and precision of the data. Most samples represent discrete concentrations in time and space; with sampling points frequently limited in both dimensions, sparse data sets are heavily extrapolated and the quality of data further limited.

Methods are presented for characterizing contaminants in water (groundwater and surface waters) and indoor air. These techniques are integrative, providing information averaged over time and/or space, as opposed to instantaneous point measurements. Contaminants are concentrated from the environment, making these methods applicable to trace contaminants. These methods have the potential to complement existing techniques, providing the practitioner with opportunities to reduce costs and improve the quality of the data used in decision making.

A conceptual model for integrative sampling of environmental waters is developed and a literature review establishes an advantage in precision for active samplers. A programmable sampler was employed to measure the concentration of chromate in a shallow aquifer exhibiting time-dependent contaminant concentrations, providing a unique data set and sustainability benefits. The analysis of heat exchanger condensate, a waste stream generated by air conditioning, is demonstrated in a non-intrusive method for indoor air quality assessment. In sum, these studies present new opportunities for effective, sustainable environmental characterization.

The influence of temperature on soil engineering properties is a major concern in the design of engineering systems such as radioactive waste disposal barriers, ground source heat pump systems and pavement structures. In particular, moisture redistribution under pavement systems might lead to changes in unbound material stiffness that will affect pavement performance. Accurate measurement of thermal effects on unsaturated soil hydraulic properties may lead to reduction in design and construction costs. This thesis presents preliminary results of an experimental study aimed at determining the effect of temperature on the soil water characteristic curve (SWCC) and the unsaturated hydraulic conductivity function (kunsat). Pressure plate devices with volume change control were used to determine the SWCC and the instantaneous profile method was used to obtain the kunsat function. These properties were measured on two fine-grained materials subjected to controlled temperatures of 5oC, 25oC and 40oC. The results were used to perform a sensitivity analysis of the effect of temperature changes on the prediction of moisture movement under a covered area. In addition, two more simulations were performed where changes in hydraulic properties were done in a stepwise fashion. The findings were compared to field measured water content data obtained on the subgrade material of the FAA William Hughes test facility located in Atlantic City. Results indicated that temperature affects the unsaturated hydraulic properties of the two soils used in the study. For the DuPont soil, a soil with high plasticity, it was found that the water retention was higher at low temperatures for suction levels lower than about 10,000 kPa; while the kunsat functions at the three temperatures were not significantly different. For the County soil, a material with medium plasticity, it was found that it holds around 10% more degree of saturation at 5°C than that at 40°C for suction levels higher than about 1,000 kPa; while the hydraulic conductivity at 40°C was at least one order of magnitude higher than that at 5°C, for suction levels higher than 1,000 kPa. These properties were used to perform two types of numerical analyses: a sensitivity analysis and stepwise analysis. Absolute differences between predicted and field measured data were considered to be acceptable, ranging from 4.5% to 9% for all simulations. Overall results show an improvement in predictions when non-isothermal conditions were used over the predictions obtained with isothermal conditions.

Expansive soils impose challenges on the design, maintenance and long-term stability of many engineered infrastructure. These soils are composed of different clay minerals that are susceptible to changes in moisture content. Expansive clay soils wreak havoc due to their volume change property and, in many cases, exhibit extreme swelling and shrinking potentials. Understanding what type of minerals and clays react in the presence of water would allow for a more robust design and a better way to mitigate undesirable soil volume change. The relatively quick and widely used method of X-ray Diffraction (XRD) allows identifying the type of minerals present in the soil. As part of this study, three different clays from Colorado, San Antonio Texas, and Anthem Arizona were examined using XRD techniques. Oedometer-type testing was simultaneously preformed in the laboratory to benchmark the behavior of these soils. This analysis allowed performing comparative studies to determining if the XRD technique and interpretation methods currently available could serve as quantitative tools for estimating swell potential through mineral identification. The soils were analyzed using two different software protocols after being subjected to different treatment techniques. Important observations include the formation of Ettringite and Thaumasite, the effect of mixed-layer clays in the interpretation of the data, and the soils being subject to Gypsification. The swelling data obtained from the oedometer-type laboratory testing was compared with predictive swelling functions available from literature. A correlation analysis was attempted in order to find what index properties and mineralogy parameters were most significant to the swelling behavior of the soils. The analysis demonstrated that Gypsification is as important to the swelling potential of the soil as the presence of expansive clays; and it should be considered in the design and construction of structures in expansive soils. Also, the formation of Ettringite and Thaumasite observed during the treatment process validates the evidence of Delayed Ettringite Formation (DEF) reported in the literature. When comparing the measured results with a proposed method from the University of Texas at Arlington (UTA), it was found that the results were somewhat indicative of swell potential but did not explain all causes for expansivity. Finally, it was found that single index properties are not sufficient to estimate the free swell or the swell pressure of expansive soils. In order to have a significant correlation, two or more index properties should be combined when estimating the swell potential. When properties related to the soil mineralogy were correlated with swell potential parameters, the amount of Gypsum present in the soil seems to be as significant to the swell behavior of the soil as the amount of Smectite found.

Characterization of petroleum spill site source zones directly influences the selection of corrective action plans and frequently affects the success of remediation efforts. For example, simply knowing whether or not nonaqueous phase liquid (NAPL) is present, or if there is chemical storage in less hydraulically accessible regions, will influence corrective action planning. The overarching objective of this study was to assess if macroscopic source zone features can be inferred from dissolved concentration vs. time data. Laboratory-scale physical model studies were conducted for idealized sources; defined as Type-1) NAPL-impacted high permeability zones, Type-2) NAPL-impacted lower permeability zones, and Type-3) dissolved chemical matrix storage in lower permeability zones. Aquifer source release studies were conducted using two-dimensional stainless steel flow-through tanks outfitted with sampling ports for the monitoring of effluent concentrations and flow rates. An idealized NAPL mixture of key gasoline components was used to create the NAPL source zones, and dissolved sources were created using aqueous solutions having concentrations similar to water in equilibrium with the NAPL sources. The average linear velocity was controlled by pumping to be about 2 ft/d, and dissolved effluent concentrations were monitored daily. The Type-1 experiment resulted in a source signature similar to that expected for a relatively well-mixed NAPL source, with dissolved concentrations dependent on chemical solubility and initial mass fraction. The Type-2 and Type-3 experiments were conducted for 320 d and 190 d respectively. Unlike the Type-1 experiment, the concentration vs. time behavior was similar for all chemicals, for both source types. The magnitudes of the effluent concentrations varied between the Type-2 and Type-3 experiments, and were related to the hydrocarbon source mass. A fourth physical model experiment was performed to identify differences between ideal equilibrium behavior and the source concentration vs. time behavior observed in the tank experiments. Screening-level mathematical models predicted the general behavior observed in the experiments. The results of these studies suggest that dissolved concentration vs. time data can be used to distinguish between Type-1 sources in transmissive zones and Type-2 and Type-3 sources in lower permeability zones, provided that many years to decades of data are available. The results also suggest that concentration vs. time data alone will be insufficient to distinguish between NAPL and dissolved-phase storage sources in lower permeability regions.