For this dissertation, three separate papers explore the study areas of the western Grand Canyon, the Grand Staircase (as related to Grand Canyon) and Desolation Canyon on the Green River in Utah.

In western Grand Canyon, I use comparative geomorphology between the Grand Canyon and the Grand Wash Cliffs (GWC). We propose the onset of erosion of the GWC is caused by slip on the Grand Wash Fault that formed between 18 and 12 million years ago. Hillslope angle and channel steepness are higher in Grand Canyon than along the Grand Wash Cliffs despite similar rock types, climate and base level fall magnitude. These experimental controls allow inference that the Grand Canyon is younger and eroding at a faster rate than the Grand Wash Cliffs.

The Grand Staircase is the headwaters of some of the streams that flow into Grand Canyon. A space-for-time substitution of erosion rates, supported by landscape simulations, implies that the Grand Canyon is the result of an increase in base level fall rate, with the older, slower base level fall rate preserved in the Grand Staircase. Our data and analyses also support a younger, ~6-million-year estimate of the age of Grand Canyon that is likely related to the integration of the Colorado River from the Colorado Plateau to the Basin and Range. Complicated cliff-band erosion and its effect on cosmogenic erosion rates are also explored, guiding interpretation of isotopic data in landscapes with stratigraphic variation in quartz and rock strength.

Several hypotheses for the erosion of Desolation Canyon are tested and refuted, leaving one plausible conclusion. I infer that the Uinta Basin north of Desolation Canyon is eroding slowly and that its form represents a slow, stable base level fall rate. Downstream of Desolation Canyon, the Colorado River is inferred to have established itself in the exhumed region of Canyonlands and to have incised to near modern depths prior to the integration of the Green River and the production of relief in Desolation Canyon. Analysis of incision and erosion rates in the region suggests integration is relatively recent.

The search for life on Mars is a major NASA priority. A Mars Sample Return

(MSR) mission, Mars 2020, will be NASA's next step towards this goal, carrying an instrument suite that can identify samples containing potential biosignatures. Those samples will be later returned to Earth for detailed analysis. This dissertation is intended to inform strategies for fossil biosignature detection in Mars analog samples targeted for their high biosignature preservation potential (BPP) using in situ rover-based instruments. In chapter 2, I assessed the diagenesis and BPP of one relevant analog habitable Martian environment: a playa evaporite sequence within the Verde Formation, Arizona. Coupling outcrop-scale observations with laboratory analyses, results revealed four diagenetic pathways, each with distinct impacts on BPP. When MSR occurs, the sample mass returned will be restricted, highlighting the importance of developing instruments that can select the most promising samples for MSR. Raman spectroscopy is one favored technique for this purpose. Three Raman instruments will be sent onboard two upcoming Mars rover missions for the first time. In chapters 3-4, I investigated the challenges of Raman to identify samples for MSR. I examined two Raman systems, each optimized in a different way to mitigate a major problem commonly suffered by Raman instruments: background fluorescence. In Chapter 3, I focused on visible laser excitation wavelength (532 nm) gated (or time-resolved Raman, TRR) spectroscopy. Results showed occasional improvement over conventional Raman for mitigating fluorescence in samples. It was hypothesized that results were wavelength-dependent and that greater fluorescence reduction was possible with UV laser excitation. In Chapter 4, I tested this hypothesis with a time-resolved UV (266 nm) gated Raman and UV fluorescence spectroscopy capability. I acquired Raman and fluorescence data sets on samples and showed that the UV system enabled identifications of minerals and biosignatures in samples with high confidence. The results obtained in this dissertation may inform approaches for MSR by: (1) refining models for biosignature preservation in habitable Mars environments; (2) improving sample selection and caching strategies, which may increase the success of Earth-based biogenicity studies; and (3) informing the development of Raman instruments for upcoming rover-based missions.

Amazonia, inhabited and investigated for millennia, continues to astonish scientists with its cultural and natural diversity. Although Amazonia is rapidly changing, its vast and varied landscape still contains a complex natural pharmacopeia. The Amazonian tribes have accrued valuable environmental and geological knowledge that can be studied. This dissertation demonstrates that Indigenous Knowledge considered alongside Western Science can enhance our understanding of the relationship of people to geological materials and hydrological resources, and reveal mineral medicines with practical applications.

I used methods from anthropology and geology to explore the geological knowledge of the Uitoto, a tribe of the Colombian Amazon. The Uitoto use two metaphors to describe Earth systems: 1. the earth is a body, and 2. the Amazon is a tree. I found that they classify surface-water systems according to observable characteristics and use mineral clays to treat various maladies. I argue that Uitoto knowledge about Amazonian mineral resources and surface water is practical, empirically–based and, in many cases, more nuanced than mainstream scientific knowledge.

I studied the mode of action of a natural antibacterial clay from the Colombian Amazon (AMZ) to discover whether the Uitoto’s claims about the clay’s medicinal values was verifiable using the methods of Western Science. Natural antibacterial clays can inhibit the growth of human pathogens. Methods from microbiology and geochemistry were combined to evaluate the mineral-microbe interactions that inhibit growth of model Gram-negative (Escherichia coli) and Gram-positive (Bacillus subtilis) bacteria. The AMZ antibacterial clay contains 45 % kaolinites and 30 % smectites. Its high surface area maintains an acidic environment (pH 4.5) and releases high concentrations of aluminum. Aluminum accumulates in the outer membrane of E. coli by binding to phospholipids. Furthermore, the membrane’s permeability increases due to synergistic effects between aluminum and transition metals released from the AMZ (i.e. Fe, Cu). The changes in the membrane may compromise its function as a barrier. Understanding the antibacterial mechanism of AMZ is key for its safe use as a natural product. These findings can help us harness the capabilities of antibacterial clays more efficiently.

Lastly, I integrated the results of this work in place-based, cross-cultural educational materials tailored for the tribal schools in the Colombian Amazon. The design of the units was informed by principles of curriculum design and successful pedagogic approaches for Native American students. The purpose of these educational materials is to return the results of research, enhance learning and participation of indigenous peoples in geosciences, and respond to the multicultural and plurilingual educational needs in countries such as Colombia.

The historic Cacachilas mining district is located in Baja California Sur, approximately 20 kilometers east of La Paz, and has a series of gold- and silver-hosted veins, faults, and shear zones within Cretaceous granodioritic plutons. The remote geographic location and past political events within Mexico left the district essentially unexplored after the late 1800s, when the Mexican Revolution began. More recent discovery of gold deposits along the Baja peninsula instigated a renewed interest in mineralization in the Sierra Cacachilas. The area lacks detailed previous geologic data, so this study focused on characterizing the controls of mineralization and the locations of mineralized trends of deposits within the northeastern Sierra Cacachilas, with a goal toward helping assess economic viability of the deposits. I mapped surficial geologic data, such as outcrop locations, alteration assemblages, limonite intensities, and structural measurements. I then synthesized these into geologic maps and cross sections. I combined field data with geochemical assays and structural plots to better characterize individual historic district trends and newly located trends to understand the distribution of mineralization at surface and at depth. Lastly, I synthesized geology of the Sierra Cacachilas with other gold and silver deposits located in the southern Baja peninsula to better characterize the mineralization and deposit style of the Cacachilas district.

Mineralization in the northeastern Sierra Cacachilas is mainly restricted to steeply dipping quartz veins, faults, and brittle-ductile shear zones that trend generally northeast. Some veins are en-echelon within the mineralized zones, implying some lateral movement along the zones. Veins are dominated by milky to clear quartz with trace sulfides, abundant limonite (after sulfides), and local open-space textures. Mineralization is interpreted to be intermediate between classic epithermal and mesothermal veins. Within mineralized trends and commonly associated with mineralization are greisen-like zones that are defined by intense sericitic to muscovitic overprint, trend northeast, and are with or without sulfides. The intensity of sulfide abundance and limonitic alteration after sulfides within and near mineralized zones is overall a good guide to mineralization. Based on past reports and on my recent studies, the Cacachilas district has very promising potential for relatively small, high-grade deposits.

ABSTRACT

The Sentinel-Arlington Volcanic Field (SAVF) is the Sentinel Plains lava field and associated volcanic edifices of late Cenozoic alkali olivine basaltic lava flows and minor tephra deposits near the Gila Bend and Painted Rock Mountains, 65 km-100km southwest of Phoenix, Arizona. The SAVF covers ~600 km2 and consists of 21+ volcanic centers, primarily low shield volcanoes ranging from 4-6 km in diameter and 30-200 m in height. The SAVF represents plains-style volcanism, an emplacement style and effusion rate intermediate between flood volcanism and large shield-building volcanism. Because of these characteristics, SAVF is a good analogue to small-volume effusive volcanic centers on Mars, such as those seen the southern flank of Pavonis Mons and in the Tempe Terra region of Mars. The eruptive history of the volcanic field is established through detailed geologic map supplemented by geochemical, paleomagnetic, and geochronological analysis.

Paleomagnetic analyses were completed on 473 oriented core samples from 58 sites. Mean inclination and declination directions were calculated from 8-12 samples at each site. Fifty sites revealed well-grouped natural remanent magnetization vectors after applying alternating field demagnetization. Thirty-nine sites had reversed polarity, eleven had normal polarity. Fifteen unique paleosecular variation inclination and declination directions were identified, six were represented by more than one site with resultant vectors that correlated within a 95% confidence interval. Four reversed sites were radiometrically dated to the Matuyama Chron with ages ranging from 1.08 ± 0.15 Ma to 2.37 ± 0.02 Ma; and one normal polarity site was dated to the Olduvai normal excursion at 1.91 ± 0.59 Ma. Paleomagnetic correlations within a 95% confidence interval were used to extrapolate radiogenic dates. Results reveal 3-5 eruptive stages over ~1.5 Ma in the early Pleistocene and that the SAVF dammed and possibly diverted the lower Gila River multiple times. Preliminary modeling of the median clast size of the terrace deposits suggests a maximum discharge of ~11300 cms (~400,000 cfs) was necessary to transport observed sediment load, which is larger than the historically recorded discharge of the modern Gila River.

This is a qualitative study about sources of self-efficacy and roles of assistive technologies (AT) associated with the science, technology, engineering and mathematics (STEM) choice and participation of STEM professionals and graduate students with sensory and orthopedic disabilities. People with disabilities are underrepresented in STEM, which can be traced back along the STEM pipeline to early undergraduate participation in STEM. Little research exists, however, about pathways and factors associated with successful STEM participation for people with disabilities at any point along their trajectories. Eighteen STEM professionals and graduate students with sensory and orthopedic disabilities were interviewed for this study. Sources of self-efficacy were sought from interview transcripts, as were emergent themes associated with the types, uses and roles of AT. Findings suggest that people with sensory and orthopedic disabilities weigh sources of self-efficacy differently from white males without disabilities in STEM and more like other underrepresented minorities in STEM. Social persuasions were most frequently reported and in far more detail than other sources, suggesting that this source may be most impactful in the development of self-efficacy beliefs for this group. Additionally, findings indicate that AT is critical to the successful participation of people with sensory and orthopedic disabilities in STEM at all points along their STEM pathways. Barriers center around issues of access to full engagement in mainstream STEM classrooms and out of school opportunities as well as the impact of ill-informed perceptions about the capabilities of people with disabilities held by parents, teachers and college faculty who can act as gatekeepers along STEM pathways. Gaps in disability specialists' knowledge about STEM-specific assistive technologies, especially at the college level, are also problematic. The prevalence of mainstream public school attendance reported by participants indicates that classroom teachers and disability-related educators have important roles in providing access to STEM mastery experiences as well as providing positive support and high expectations for students with disabilities. STEM and disability-based networks served to provide participants with role models, out of school STEM learning experiences and important long-term social connections in STEM communities.

This dissertation is presented in two sections. First, I explore two methods of using stable isotope analysis to trace environmental and biogeochemical processes. Second, I present two related studies investigating student understanding of the biogeochemical concepts that underlie part one. Fe and Hg are each biogeochemically important elements in their own way. Fe is a critical nutrient for phytoplankton, while Hg is detrimental to nearly all forms of life. Fe is often a limiting factor in marine phytoplankton growth. The largest source, by mass, of Fe to the open ocean is windblown mineral dust, but other more soluble sources are more bioavailable. To look for evidence of these non-soil dust sources of Fe to the open ocean, I measured the isotopic composition of aerosol samples collected on Bermuda. I found clear evidence in the fine size fraction of a non-soil dust Fe source, which I conclude is most likely from biomass burning. Widespread adoption of compact fluorescent lamps (CFL) has increased their importance as a source of environmental Hg. Isotope analysis would be a useful tool in quantifying this impact if the isotopic composition of Hg from CFL were known. My measurements show that CFL-Hg is isotopically fractionated, in a unique pattern, during normal operation. This fractionation is large and has a distinctive, mass-independent signature, such that CFL Hg can be uniquely identified from other sources. Misconceptions research in geology has been a very active area of research, but student thinking regarding the related field of biogeochemistry has not yet been studied in detail. From interviews with 40 undergraduates, I identified over 150 specific misconceptions. I also designed a multiple-choice survey (concept inventory) to measure understanding of these same biogeochemistry concepts. I present statistical evidence, based on the Rasch model, for the reliability and validity of this instrument. This instrument will allow teachers and researchers to easily quantify learning outcomes in biogeochemistry and will complement existing concept inventories in geology, chemistry, and biology.

Earth's topographic surface forms an interface across which the geodynamic and geomorphic engines interact. This interaction is best observed along crustal margins where topography is created by active faulting and sculpted by geomorphic processes. Crustal deformation manifests as earthquakes at centennial to millennial timescales. Given that nearly half of Earth's human population lives along active fault zones, a quantitative understanding of the mechanics of earthquakes and faulting is necessary to build accurate earthquake forecasts. My research relies on the quantitative documentation of the geomorphic expression of large earthquakes and the physical processes that control their spatiotemporal distributions. The first part of my research uses high-resolution topographic lidar data to quantitatively document the geomorphic expression of historic and prehistoric large earthquakes. Lidar data allow for enhanced visualization and reconstruction of structures and stratigraphy exposed by paleoseismic trenches. Lidar surveys of fault scarps formed by the 1992 Landers earthquake document the centimeter-scale erosional landforms developed by repeated winter storm-driven erosion. The second part of my research employs a quasi-static numerical earthquake simulator to explore the effects of fault roughness, friction, and structural complexities on earthquake-generated deformation. My experiments show that fault roughness plays a critical role in determining fault-to-fault rupture jumping probabilities. These results corroborate the accepted 3-5 km rupture jumping distance for smooth faults. However, my simulations show that the rupture jumping threshold distance is highly variable for rough faults due to heterogeneous elastic strain energies. Furthermore, fault roughness controls spatiotemporal variations in slip rates such that rough faults exhibit lower slip rates relative to their smooth counterparts. The central implication of these results lies in guiding the interpretation of paleoseismically derived slip rates that are used to form earthquake forecasts. The final part of my research evaluates a set of Earth science-themed lesson plans that I designed for elementary-level learning-disabled students. My findings show that a combination of concept delivery techniques is most effective for learning-disabled students and should incorporate interactive slide presentations, tactile manipulatives, teacher-assisted concept sketches, and student-led teaching to help learning-disabled students grasp Earth science concepts.

Science, Technology, Engineering & Mathematics (STEM) careers have been touted as critical to the success of our nation and also provide important opportunities for access and equity of underrepresented minorities (URM's). Community colleges serve a diverse population and a large number of undergraduates currently enrolled in college, they are well situated to help address the increasing STEM workforce demands. Geoscience is a discipline that draws great interest, but has very low representation of URM's as majors. What factors influence a student's decision to major in the geosciences and are community college students different from research universities in what factors influence these decisions? Through a survey-design mixed with classroom observations, structural equation model was employed to predict a student's intent to persist in introductory geology based on student expectancy for success in their geology class, math self-concept, and interest in the content. A measure of classroom pedagogy was also used to determine if instructor played a role in predicting student intent to persist. The targeted population was introductory geology students participating in the Geoscience Affective Research NETwork (GARNET) project, a national sampling of students in enrolled in introductory geology courses. Results from SEM analysis indicated that interest was the primary predictor in a students intent to persist in the geosciences for both community college and research university students. In addition, self-efficacy appeared to be mediated by interest within these models. Classroom pedagogy impacted how much interest was needed to predict intent to persist, in which as classrooms became more student centered, less interest was required to predict intent to persist. Lastly, math self-concept did not predict student intent to persist in the geosciences, however, it did share variance with self-efficacy and control of learning beliefs, indicating it may play a moderating effect on student interest and self-efficacy. Implications of this work are that while community college students and research university students are different in demographics and content preparation, student-centered instruction continues to be the best way to support student's interest in the sciences. Future work includes examining how math self-concept may play a role in longitudinal persistence in the geosciences.

ABSTRACT The accretion of juvenile island-arc lithosphere by convergent tectonism during the Paleoproterozoic, in conjunction with felsic volcanism, resulted in the assembly, ductile to partial brittle deformation, uplift, and northwest-directed thrusting of rocks in the McDowell Mountains region and adjacent areas in the Mazatzal Orogenic belt. Utilizing lithologic characteristics and petrographic analysis of the Proterozoic bedrock, a correlation to the Alder series was established, revising the stratigraphic sequences described by earlier works. The central fold belt, composed of an open, asymmetric syncline and an overturned, isoclinal anticline, is cut by an axial-plane parallel reactivated thrust zone that is intruded by a deformed Paleoproterozoic mafic dike. Finite strain analyses of fold geometries, shear fabrics, foliations, fold vergence, and strained clasts point to Paleoproterozoic northwest-directed thrusting associated with the Mazatzal orogen at approximately 1650 million years ago. Previous studies constrained the regional P-T conditions to at least the upper andalusite-kyanite boundary at peak metamorphic conditions, which ranged from 4-6 kilobars and 350-450⁰ Celsius, although the plasticity of deformation in a large anticlinal core suggests that this represents the low end of the P-T conditions. Subsequent to deformation, the rocks were intruded by several granitoid plutons, likely of Mesoproterozoic age (1300-1400 Ma). A detailed analysis of Proterozoic strain solidly places the structure of the McDowell Mountains within the confines of the Mazatzal Orogeny, pending any contradictory geochronological data.