Political boundaries often divide ecosystems and create the challenge of conserving the ecosystem across borders. Through transboundary ecosystem management multiple groups can come together and manage the ecosystem that spans their borders collaboratively. In the United States there are several…
Political boundaries often divide ecosystems and create the challenge of conserving the ecosystem across borders. Through transboundary ecosystem management multiple groups can come together and manage the ecosystem that spans their borders collaboratively. In the United States there are several examples of ecosystems that span borders, such as the Sonoran Desert along the US-Mexico frontier and the Rocky Mountains running through the US and Canada. To gain insight into what leads to effective transboundary resource management I compared two case studies that manage resources over borders with multiple collaborators: Glacier National Park and Organ Pipe Cactus National Monument. These two cases offer contrasting ecosystems and backgrounds in transboundary resource management in the United States. To compare the cases I coded them using a collaborative governance codebook (Schoon et al. 2020). The codebook uses a Context-Mechanisms-Outcomes framework to identify aspects of collaborative governance and contextual factors present in each park (Pawson & Tilley 1997; Salter & Kothari, 2014). Once coded, the cases were compared to identify what aspects were similar and different in the parks to help potentially explain what features did or did not lead to effective transboundary resource management.
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Food Insecurity amongst college students is a growing issue in today’s society due to the lack of access to food and programs commonly used for food assistance. Logistical issues present a unique challenge in feeding food-insecure college students. And the…
Food Insecurity amongst college students is a growing issue in today’s society due to the lack of access to food and programs commonly used for food assistance. Logistical issues present a unique challenge in feeding food-insecure college students. And the stigma associated with this food insecurity may cause students to avoid seeking assistance. Students are only able to address this challenge through 3 main solutions: pantries, meal swipe programs, and drive-thru pantries. Food insecurity challenges that individuals face can be found on Arizona State University campus. Currently, food insecurity is only addressed on campus through pantries and distribution centers. These are run through student-led organizations and typically are partnered with food banks or charities within the area. These solutions can be inconsistent and deal with logistic challenges like space, storage, and transportation. One of the proposed solutions to these challenges is programs like the Food Recovery Network.
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Phenolic polymers such as polyphenols and polyphenylenes are generated industrially for several applications but are typically associated with harsh reaction conditions and environmentally hazardous chemicals, such as formaldehyde. Additionally, hydroxycinnamic acids, such as p-coumaric acid (CA), are found in high…
Phenolic polymers such as polyphenols and polyphenylenes are generated industrially for several applications but are typically associated with harsh reaction conditions and environmentally hazardous chemicals, such as formaldehyde. Additionally, hydroxycinnamic acids, such as p-coumaric acid (CA), are found in high concentrations in underutilized lignin-derived hydrolysates and represent a renewable and sustainable feedstock for the production of various aromatics and phenolics. To that end, recently a strain of Corynebacterium glutamicum has been developed by the Joint Bioenergy Institute to express a Phenolic Acid Decarboxylase (PAD), which can convert CA into 4-vinylphenol (4VP). 4VP is cytotoxic but can be polymerized by ligninolytic enzymes such as laccases or peroxidases into less-toxic poly(4-vinylphenol) (PVP). This work investigates the potential of polymerizing 4VP in situ by adding ligninolytic enzymes into the fermentation media to polymerize 4VP into PVP as it is produced, while reducing cellular toxicity to aid in chemical conversion.
The engineered C. glutamicum strain was cultured in the presence of CA to produce 4VP, with a maximum yield of 80.75%. Simultaneously, two ligninolytic enzymes, laccase and horseradish peroxidase (HRP), were explored in an in vitro experiment for their ability to polymerize 4VP, with laccase achieving full polymerization within 45 minutes and HRP able to polymerize 54.06% of 4VP in 24 hours. The resulting polymers were further analyzed by using gas permeation chromatography - nuclear magnetic resonance, validating the synthesis of PVP from 4VP with the addition of laccase or HRP. Finally, the C. glutamicum strain was evaluated for its ability to grow in the presence of hydrogen peroxide, which is a necessary reagent for HRP functionality, and it was able to reach an optical density of 3.69 within 36 hours. These findings suggest that in situ polymerization may be possible. Further work is underway to explore the enzyme kinetics at different pH, validate the potential of polymerization in situ, and study the fermentative benefits associated with in situ polymerization. This will be followed by additional analytical studies to characterize the resulting PVP.
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The COVID-19 pandemic caused uncertainty and changing public health recommendations across the world as our understanding of the SARS-CoV-2 virus changed. Following a preliminary assessment by the World Health Organization, non-steroidal anti-inflammatory drugs were said to worsen symptoms and should…
The COVID-19 pandemic caused uncertainty and changing public health recommendations across the world as our understanding of the SARS-CoV-2 virus changed. Following a preliminary assessment by the World Health Organization, non-steroidal anti-inflammatory drugs were said to worsen symptoms and should be avoided before the recommendation was subsequently revoked. There also was pain associated with infection, leading to the hypothesis that use of over-the-counter pain medication increases may correlate with increases of SARS-CoV-2 infections. Wastewater samples were collected from two communities in Tempe, AZ from December 2019 to July 2020 (n = 35) and were analyzed by liquid chromatography tandem mass spectrometry (LC-MS/MS) to identify levels of acetaminophen, ibuprofen and their metabolites, acetaminophen sulfate and carboxy-ibuprofen. Results showed 100% detection frequency of all analytes in all samples across the duration of the study. Mass loadings of acetaminophen (918.4 g day-1 +/- 354.8 g day-1) were higher than ibuprofen (182.9 g day-1 +/- 49.8 g day-1), potentially driven by flushing behaviors rather than consumption activities. However, ibuprofen was more heavily consumed than acetaminophen across all days of the study period. Comparisons to COVID-19 clinical cases data showed increased use in ibuprofen with increases in clinical cases loads, while acetaminophen showed no change, suggesting ibuprofen was the over the counter (OTC) medication of choice during the first wave of the pandemic.
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Urban heat island effect is caused by the built environment and impervious surfaces in urban areas causing the local air temperature to be significantly higher than that of near-by rural areas. This effect continues to worsen and spread nationwide as…
Urban heat island effect is caused by the built environment and impervious surfaces in urban areas causing the local air temperature to be significantly higher than that of near-by rural areas. This effect continues to worsen and spread nationwide as urban sprawl increases through land development. As more land gets paved over, more heat energy is produced and radiated into the local atmosphere. In Phoenix, urban heat island effect is expected to be the most prominent when the city has been the fastest growing metro area in the United States in this decade and continues to grow at a rapid pace. As urban heat island effects increase, climate change caused by anthropogenic activities continues to worsen. This causes drought conditions to worsen all across the American Southwest. California was the first state to enact water restrictions in response to the current drought conditions in 2015, with Nevada and Colorado following in 2021 in efforts to preserve water. Sustainable urban water systems management and design have been an emerging research area. One of the most effective systems being the reuse of greywater in irrigation. With this use of greywater for all outdoor water needs, excluding swimming pools, there is the ability to use equal amounts of outdoor water as indoor water. This increases the amount of available water for all landscaping. With increased amounts of available water, plants and vegetation will most often grow fast and larger. Larger and healthier vegetation both increase shade as well as evaporative-transpiration. Both of these can decrease the local air temperature. This research aims to investigate if and how the reuse of greywater for landscape irrigation can ultimately lead to cooler air temperatures, decreasing the urban heat island effect. In Spring 2022, I partnered with a local landscape architecture firm to examine a case study of a pilot greywater reuse system. The pilot was the basis for a larger greywater reuse system integrated into a multifamily apartment complex, currently under construction, in downtown Phoenix.
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In urban planning and design, creating emotional bonds, known as place identity, between people and their surroundings is paramount to improving the well-being of those who reside there. However, determining how to alter the built environment in order to increase…
In urban planning and design, creating emotional bonds, known as place identity, between people and their surroundings is paramount to improving the well-being of those who reside there. However, determining how to alter the built environment in order to increase place identity is a difficult task to achieve. Walkability is a good mechanistic link between the built environment and place identity. Walkability is comprised of a suite of factors that take into consideration both the natural and built environment. This thesis aims to determine if walkability is positively correlated with place identity in an extreme climate such as Phoenix. To test this, ecosystem services and disservices are used as factors to measure overall walkability. We found that access to recreational opportunities, aesthetic features of the pathway, and safety were all significant predictors of place identity. This has positive implications for walkable infrastructure to be strengthened in desert cities.
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This thesis explores what factors have hindered the effectiveness of international aid in promoting sustainable development—an approach that focuses on not just immediate responses, but long-term changes that promote the well-being of current and future generations in relation to environmental degradation, social equity, and economic growth—in Haiti.
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The project goal is aimed to research the most pressing issues facing the lithium supply chain today. It then is tasked with charting a path into the future through strategic recommendations that will help reduce risk, and make a greener, cleaner, and more ethical supply chain.
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Climate change risks such as rising sea-levels, prolonged droughts, and extreme coastal weather events, are devastating for Small Island Developing States (SIDS) where both their homes and livelihoods are highly interdependent upon the ocean. These SIDS have no other viable…
Climate change risks such as rising sea-levels, prolonged droughts, and extreme coastal weather events, are devastating for Small Island Developing States (SIDS) where both their homes and livelihoods are highly interdependent upon the ocean. These SIDS have no other viable choice but to adapt to their ever-changing environments and the rising disaster risks compounded by climate change. Although SIDS tend to receive significant attentions for the adverse impacts of climate change, less is known about the place-based adaptation measures as well as people’s lived experiences with sea-level rise, inundation, tropical storms, droughts, and more. Considering the vast area that the SIDS’ nations cover, the type of climate adaptation measures adopted may vary due to the respective country’s vulnerability and adaptive capacity, as some are more comprehensive and effective than others. This study directly responds to the existing gap in our understanding of how different nations within SIDS are prioritizing and strategizing their adaptation measures with the following research questions: “What are key adaptation strategies practiced in Small Island Developing States (SIDS) to address impacts of climate change? Are there similarities or differences in the adaptation strategies pursued by SIDS?” This study uses a conceptual framework of disaster risk and climate change adaptation developed by the IPCC AR5 (2014) to systematically review over 107 peer-reviewed journal articles, scientific reports, and a few videos. Using a systematic literature view approach as the primary research method, this study assembled, categorized, and analyzed the national as well as sub-national adaptation measures—social, institutional, and structural--of two representative countries: 1) Kiribati (a small, low-lying island with the higher level of exposure and vulnerability to climate change), and 2) Fiji (the second biggest island in the South Pacific known for bigger economy and “High Islands”). The results of the study suggest that the adopted adaptation measures were reflective of the country’s historical legacy and the existing adaptive capacity. While Kiribati has historically focused more on external migration of displaced people and more recently has prioritized structural adaptation practices (e.g., construction of coastal seawall), Fiji has been able to leverage its bigger economy and technical resources to develop more comprehensive institutional, social, and structural adaptation measures. However, it is also important to recognize that the other internal and external factors, mainly geophysical setting (low elevation of Kiribati vs the high islands of Fiji) also contribute the level of vulnerability these nations face.
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Since the 1980’s, there has been a growing interest in the concept of sustainability. The prime directive of sustainability is to balance the needs of economics, environmental health, and human society. The change in the global climate, loss of biodiversity,…
Since the 1980’s, there has been a growing interest in the concept of sustainability. The prime directive of sustainability is to balance the needs of economics, environmental health, and human society. The change in the global climate, loss of biodiversity, increased levels of pollution, and general trend toward resource scarcity have all increased the momentum of the contemporary sustainability movement. Simultaneously, poverty and nutrition scarcity have attracted many to sustainability’s principles of resource equity. What one can gather from the diversity of sustainability’s intended functions is that it’s meant to solve several problems at once. In another sense, the most impactful sustainability solutions are multipurpose. This is not to say that any given solution is a panacea. On the contrary, sustainability advocates often dispute the existence of so-called “silver bullets” for these global issues. While this tends to reign true, it does not stop policy makers, communities, or researchers from attempting to employ multifaceted solutions. One such example is the myriad of sustainability issues associated with industrial agriculture. With the compounding issues of high water consumption, habitat destruction via land use change, biodiversity loss and climate change, industrial agriculture appears to be a damaging system. Areas like Arizona are projected to be affected by many of these issues. It thus stands to reason that if Arizona is to aggressively address its long-term drought, as well as global sustainability issues, a systematic change in farming practices needs to be made. Firstly, an analysis of the agricultural and water histories of Arizona will highlight the events most relevant to the region’s contemporary issues. Following this, the analysis will frame the greater problem through specific pieces of evidence associated with water scarcity in Arizona. Then, a summary of findings will illustrate the fundamental theories surrounding regenerative agriculture and three of its alternative forms: permaculture, dryland farming, and carbon farming. These theories will be instrumental in recommending a useful conception of regenerative agriculture for Arizona; it will be known as a Regenerative Dryland Farming System (RDFS). The extent and utility of current solutions will then be explored. The remainder of the section will illustrate the principles of the RDFSs, explore their potential weaknesses, and recommend policy for their successful deployment. Overall, it will be argued that RDFSs should fully replace industrial agriculture in Arizona. This will be vital in addressing the nine planetary boundaries and freshwater reality of the region.
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