Tissintite-II and Other High Pressure/Temperature Minerals in Lunar Meteorite NWA 13967

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Description

Lunar meteorites are created when an asteroid impacts the Moon. In such events, the lunar surface, known as regolith, can experience extreme pressures and temperature conditions. Some of this regolith material can be ejected from the Moon and enter interplanetary

Lunar meteorites are created when an asteroid impacts the Moon. In such events, the lunar surface, known as regolith, can experience extreme pressures and temperature conditions. Some of this regolith material can be ejected from the Moon and enter interplanetary space where it can be captured by Earth's gravity. Even after falling to Earth, the minerals of lunar meteorites preserve the history and conditions of lunar impact processes. One such mineral that has gained attention recently is tissintite due to its relatively specific temperature and pressure formation conditions. The lunar meteorite NWA 13967 and its mineral assemblage provided an opportunity for comparison to other lunar meteorites (Zhang et al. 2021). Based on its mineralogy and petrography, NWA 13967 likely experienced peak pressures of 18 to 24 GPa and peak temperatures above 2000℃, as indicated by the presence of intergranular melt, vesicles, and corundum. The occurrence of tissintite-II and coesite suggest crystallization during cooling and decompression, while other high pressure minerals likely back-transformed to lower pressure polymorphs.

Date Created
2022-05
Agent

Tephrostratigraphy of Pliocene Drill Cores from Kenya and Ethiopia, and Pleistocene Exposures in the Ledi-Geraru Research Project Area, Ethiopia: Geological Context for the Evolution of Australopithecus and Homo

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Description
East African extensional basins have played a crucial role in revealing the evolution and characteristics of the early stages of continental rifting and for providing the geological context of hominin evolution and innovation. The numerous volcanic eruptions, rapid sedimentation and

East African extensional basins have played a crucial role in revealing the evolution and characteristics of the early stages of continental rifting and for providing the geological context of hominin evolution and innovation. The numerous volcanic eruptions, rapid sedimentation and burial, and subsequent exposure through faulting and erosion, provide excellent conditions for the preservation of tectonic history, paleoenvironment data, and vertebrate fossils. The reconstruction of depositional environments and provision of geochronologic frameworks for hominin sites have been largely provided by geologic investigations in conjunction with paleontological studies, like the Ledi-Geraru Research Project (LGRP). High-resolution paleoclimate records that can be directly linked to hominin fossil outcrops have been developed by the Hominin Sites and Paleolakes Drilling Project (HSPDP) which collected sedimentary-paleolake cores at or near key hominin fossil sites.

Two chapters of this dissertation are a result of research associated with the HSPDP. For HSPDP, I establish a tephrostratigraphic framework for the drill cores from the Northern Awash (Afar, Ethiopia) and Baringo-Tugen Hills-Barsemoi (Kenya) HSPDP sites. I characterize and fingerprint tephra through glass shard and feldspar phenocryst geochemistry. From tephra geochemical analyses, I establish chronostratigraphic ties between the HSPDP cores’ high-resolution paleoclimate records to outcrop stratigraphy which are associated with hominin fossils sites.

Three chapters of this dissertation are a result of field work with the LGRP. I report new geological investigations (stratigraphic, tectonic, and volcanic) of two previously unmapped regions from the eastern Ledi-Geraru (ELG), Asboli and Markaytoli. Building upon this research I present interpretations from tephra analyses, detailed stratigraphic analyses, and geologic mapping, of the Pleistocene (~2.6 to < 2.45 Ma) basin history for the LGRP. My work with the LGRP helps to reconstruct a more complete Early Pleistocene depositional and geologic history of the lower Awash Valley.

Overall, this dissertation contributes to the reconstruction of hominin paleoenvironments and the geochronological framework of the Pliocene and Pleistocene faunal/hominin records. It further contributes to rift basin history in East Africa by elaborating the later structural and stratigraphic history of the lower Awash region.
Date Created
2019
Agent

(U-Th)/He, U/Pb, and radiation damage dating of the Rochechouart-Chassenon impact structure, France

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Description
It has been hypothesized that the ~25 km Rochechouart-Chassenon impact structure (RCIS) in the NW Massif Central, France, was formed during a Late Triassic (ca. 214 Ma) terrestrial impact event that produced a catena of several large craters. Testing

It has been hypothesized that the ~25 km Rochechouart-Chassenon impact structure (RCIS) in the NW Massif Central, France, was formed during a Late Triassic (ca. 214 Ma) terrestrial impact event that produced a catena of several large craters. Testing this hypothesis, and assessing its possible impacts on biological evolution, requires both accurate and precise dating of candidate impact structures. Like many of these structures, the age of the RCIS is controversial because geochronological datasets yield contradictory results, even when a single isotopic system is used; for example, the two most recent 40Ar/39Ar studies of RCIS yielded statistically inconsistent dates of 201 ± 2 Ma (2σ) and 214 ± 8 Ma (2σ). While the precision offered by various geochronometers used to date impact structures varies significantly, a fair way to assess the confidence scientists might have in the accuracy of an impact age is to establish whether or not multiple chronometers yield statistically indistinguishable ages when applied to that structure. With that in mind, I have applied the (U-Th)/He, U/Pb, and radiation damage chronometers to zircons separated from two different RCIS impactites. My best estimate of the zircon (U-Th)/He age of the impact event is 191.6 ± 9.1 Ma at the 95% confidence level. U/Pb zircon dates suggest that most zircons in the RCIS target rocks were not completely reset during impact, but a subset (n = 8) of zircons appear to have crystallized from the impact melt or to have been completely reset; these zircons indicate a U/Pb impact age of 202.6 ± 5.8 Ma (95% confidence level). Zircon radiation damage dates are highly variable, indicating that the RCIS event resulted only in partial annealing of pre-impact zircon in the country rock, but a small sub-population of zircons yielded a mean date of 211 ± 13 Ma (95% confidence level). These results – all statistically indistinguishable from the previously published 40Ar/39Ar date of 201 ± 2 Ma – collectively argue that the impact age was near the presently agreed upon Triassic-Jurassic boundary. This age raises the possibility that seismite and tsunamite deposits found in the present-day British Isles may be related to the RCIS.
Date Created
2016
Agent