Biological soil crusts (BSCs) are critical components of arid and semiarid environments and provide the primary sources of bioavailable macronutrients and increase micronutrient availability to their surrounding ecosystems. BSCs are composed of a variety of microorganisms that perform a wide range of physiological processes requiring a multitude of bioessential micronutrients, such as iron, copper, and molybdenum. This work investigated the effects of BSC activity on soil solution concentrations of bioessential elements and examined the microbial production of organic chelators, called siderophores. I found that aluminum, vanadium, copper, zinc, and molybdenum were solubilized in the action of crusts, while nickel, zinc, arsenic, and zirconium were immobilized by crust activity. Potassium and manganese displayed behavior consistent with biological removal and mobilization, whereas phosphorus and iron solubility were dominated by abiotic processes. The addition of bioavailable nitrogen altered the effects of BSCs on soil element mobilization. In addition, I found that the biogeochemical activites of BSCs were limited by molybdenum, a fact that likely contributes to co-limitation by nitrogen. I confirmed the presence of siderophore producing microbes in BSCs. Siderophores are low-molecular weight organic compounds that are released by bacteria to increase element solubility and facilitate element uptake; siderophore production is likely the mechanism by which BSCs affect the patterns I observed in soil solution element concentrations. Siderophore producers were distributed across a range of bacterial groups and ecological niches within crusts, suggesting that siderophore production influences the availability of a variety of elements for use in many physiological processes. Four putative siderophore compounds were identified using electrospray ionization mass spectrometry; further attempts to characterize the compounds confirmed two true siderophores. Taken together, the results of my work provide information about micronutrient cycling within crusts that can be applied to BSC conservation and management. Fertilization with certain elements, particularly molybdenum, may prove to be a useful technique to promote BSC growth and development which would help prevent arid land degradation. Furthermore, understanding the effects of BSCs on soil element mobility could be used to develop useful biomarkers for the study of the existence and distribution of crust-like communities on ancient Earth, and perhaps other places, like Mars.

This research investigates Earth structure in the core-mantle boundary (CMB) region, where the solid rocky mantle meets the molten iron alloy core. At long wavelengths, the lower mantle is characterized by two nearly antipodal large low shear velocity provinces (LLSVPs), one beneath the Pacific Ocean the other beneath Africa and the southern Atlantic Ocean. However, fine-scale LLSVP structure as well as its relationship with plate tectonics, mantle convection, hotspot volcanism, and Earth's outer core remains poorly understood. The recent dramatic increase in seismic data coverage due to the EarthScope experiment presents an unprecedented opportunity to utilize large concentrated datasets of seismic data to improve resolution of lowermost mantle structures. I developed an algorithm that identifies anomalously broadened seismic waveforms to locate sharp contrasts in shear velocity properties across the margins of the LLSVP beneath the Pacific. The result suggests that a nearly vertical mantle plume underlies Hawaii that originates from a peak of a chemically distinct reservoir at the base of the mantle, some 600-900 km above the CMB. Additionally, acute horizontal Vs variations across and within the northern margin of the LLSVP beneath the central Pacific Ocean are inferred from forward modeling of differential travel times between S (and Sdiff) and SKS, and also between ScS and S. I developed a new approach to expand the geographic detection of ultra-low velocity zones (ULVZs) with a new ScS stacking approach that simultaneously utilizes the pre- and post-cursor wavefield.. Strong lateral variations in ULVZ thicknesses and properties are found across the LLSVP margins, where ULVZs are thicker and stronger within the LLSVP than outside of it, consistent with convection model predictions. Differential travel times, amplitude ratios, and waveshapes of core waves SKKS and SKS are used to investigate CMB topography and outermost core velocity structure. 1D and 2D wavefield simulations suggest that the complicated geographic distribution of observed SKKS waveform anomalies might be a result of CMB topography and a higher velocity outermost core. These combined analyses depict a lowermost mantle that is rich in fine-scale structural complexity, which advances our understanding of its integral role in mantle circulation, mixing, and evolution.

Stratification is a dominant feature of all planetary interiors. Fine-scale structure associated with layering, as well as heterogeneities hold important clues on a planet's compositional, thermal, and dynamical state, as well as its evolution. This research centers on using data from seismic arrays, networks of seismic sensors, and array processing methodologies to map the fine scale structure in the Earth's upper mantle and deep layering in the Moon - Earth and Moon are the only two planetary bodies with seismic available data for such analyses. Small-scale structure in the Earth's upper mantle can give rise to seismic wave scattering. I studied high frequency data from the Warramunga Array in Australia using array seismology. I developed and employed back-projection schemes to map the possible upper mantle scattering or reflection locations. Mapped scatterers show good correlation to strong lateral P-wave velocity gradients in tomography models and may be associated with the complex tectonic history beneath north of Australia. The minimum scale of scatterers relates to the seismic wavelength, which is roughly between 5 and 10 km in the upper mantle for the frequencies we study. The Apollo Passive Seismic Experiment (APSE) consisted of four 3-component seismometers deployed between 1969 and 1972 that continuously recorded lunar ground motion until late 1977. I studied the deep lunar interior with array methods applied to the legacy APSE dataset. The stack results suggest the presence of a solid inner and fluid outer core, overlain by a partially molten boundary layer, but their reflector impedance contrasts and reflector depths are not well constrained. With a rapidly increasing number of available modern broadband data, I developed a package, Discovery Using Ducttape Excessively (DUDE), to quickly generate plots for a comprehensive view of earthquake data. These plots facilitate discovery of unexpected phenomena. This dissertation identifies evidence for small-scale heterogeneities in Earth's upper mantle, and deeper lunar layering structure. Planetary interiors are complex with the heterogeneities on many scales, and discontinuities of variable character. This research demonstrates that seismic array methods are well-suited for interrogating heterogeneous phenomena, especially considering the recent rapid expansion of easily available dense network data.

A design methodology for a new breed of launch vehicle capable of lofting small satellites to orbit is discussed. The growing need for such a rocket is great: the United States has no capabilities in place to quickly launch and reconstitute satellite constellations. A loss of just one satellite, natural or induced, could significantly degrade or entirely eliminate critical space-based assets which would need to be quickly replaced. Furthermore a rocket capable of meeting the requirements for operationally responsive space missions would be an ideal launch platform for small commercial satellites. The proposed architecture to alleviate this lack of an affordable dedicated small-satellite launch vehicle relies upon a combination of expendable medium-range military surplus solid rocket motor assets. The dissertation discusses in detail the current operational capabilities of these military boosters and provides an outline for necessary refurbishments required to successfully place a small payload in orbit. A custom 3DOF trajectory script is used to evaluate the performance of these designs. Concurrently, a parametric cost-mass-performance response surface methodology is employed as an optimization tool to minimize life cycle costs of the proposed vehicles. This optimization scheme is centered on reducing life cycle costs per payload mass delivered rather than raw performance increases. Lastly, a novel upper-stage engine configuration using Hydroxlammonium Nitrate (HAN) is introduced and experimentally static test fired to illustrate the inherent simplicity and high performance of this high density, nontoxic propellant. The motor was operated in both pulse and small duration tests using a newly developed proprietary mixture that is hypergolic with HAN upon contact. This new propellant is demonstrated as a favorable replacement for current space vehicles relying on the heritage use of hydrazine. The end result is a preliminary design of a vehicle built from demilitarized booster assets that complements, rather than replaces, traditional space launch vehicles. This dissertation proves that such capabilities exist and more importantly that the resulting architecture can serve as a viable platform for immediate and affordable access to low Earth orbit.