This research examines lateral separation zones and sand bar slope stability using two methods: a parallelized turbulence resolving model and full-scale laboratory experiments. Lateral flow separation occurs in rivers where banks exhibit strong curvature, for instance canyon rivers, sharp meanders and river confluences. In the Colorado River, downstream Glen Canyon Dam, lateral separation zones are the principal storage of sandbars. Maximum ramp rates have been imposed to Glen Canyon Dam operation to minimize mass loss of sandbars. Assessment of the effect of restricting maximum ramp rates in bar stability is conducted using multiple laboratory experiments. Results reveal that steep sandbar faces would rapidly erode by mass failure and seepage erosion to stable slopes, regardless of dam discharge ramp rates. Thus, continued erosion of sand bars depends primarily of turbulent flow and waves. A parallelized, three-dimensional, turbulence resolving model is developed to study flow structures in two lateral separation zones located along the Colorado River in Grand Canyon. The model employs a Detached Eddy Simulation (DES) technique where variables larger than the grid scale are fully resolved, while Sub-Grid-Scale (SGS) variables are modeled. The DES-3D model is validated using ADCP flow measurements and skill metric scores show predictive capabilities of simulated flow. The model reproduces the patterns and magnitudes of flow velocity in lateral recirculation zones, including size and position of primary and secondary eddy cells and return current. Turbulence structures with a predominately vertical axis of vorticity are observed in the shear layer, becoming three-dimensional without preferred orientation downstream. The DES-3D model is coupled with a sediment advection-diffusion formulation, wherein advection is provided by the DES velocity field minus particles settling velocity, and diffusion is provided by the SGS. Results show a lateral recirculation zone having a continuous export and import of sediment from and to the main channel following a pattern of high frequency pulsations of positive deposition fluxes. These high frequency pulsations play an important role to prevent an oversupply of sediment within the lateral separation zones. Improved predictive capabilities are achieved with this model when compared with previous two- and three-dimensional quasi steady and steady models.

Air pollution is a serious problem in most urban areas around the world, which has a number of negative ecological and human health impacts. As a result, it's vitally important to detect and characterize air pollutants to protect the health of the urban environment and our citizens. An important early step in this process is ensuring that the air pollution monitoring network is properly designed to capture the patterns of pollution and that all social demographics in the urban population are represented. An important aspect in characterizing air pollution patterns is scale in space and time which, along with pattern and process relationships, is a key subject in the field of landscape ecology. Thus, using multiple landscape ecological methods, this dissertation research begins by characterizing and quantifying the multi-scalar patterns of ozone (O3) and particulate matter (PM10) in the Phoenix, Arizona, metropolitan region. Results showed that pollution patterns are scale-dependent, O3 is a regionally-scaled pollutant at longer temporal scales, and PM10 is a locally-scaled pollutant with patterns sensitive to season. Next, this dissertation examines the monitoring network within Maricopa County. Using a novel multiscale indicator-based approach, the adequacy of the network was quantified by integrating inputs from various academic and government stakeholders. Furthermore, deficiencies were spatially defined and recommendations were made on how to strengthen the design of the network. A sustainability ranking system also provided new insight into the strengths and weaknesses of the network. Lastly, the study addresses the question of whether distinct social groups were experiencing inequitable exposure to pollutants - a key issue of distributive environmental injustice. A novel interdisciplinary method using multi-scalar ambient pollution data and hierarchical multiple regression models revealed environmental inequities between air pollutants and race, ethnicity, age, and socioeconomic classes. The results indicate that changing the scale of the analysis can change the equitable relationship between pollution and demographics. The scientific findings of the scale-dependent relationships among air pollution patterns, network design, and population demographics, brought to light through this study, can help policymakers make informed decisions for protecting the human health and the urban environment in the Phoenix metropolitan region and beyond.

Droughts are a common phenomenon of the arid South-west USA climate. Despite water limitations, the region has been substantially transformed by agriculture and urbanization. The water requirements to support these human activities along with the projected increase in droughts intensity and frequency challenge long term sustainability and water security, thus the need to spatially and temporally characterize land use/land cover response to drought and quantify water consumption is crucial. This dissertation evaluates changes in `undisturbed' desert vegetation in response to water availability to characterize climate-driven variability. A new model coupling phenology and spectral unmixing was applied to Landsat time series (1987-2010) in order to derive fractional cover (FC) maps of annuals, perennials, and evergreen vegetation. Results show that annuals FC is controlled by short term water availability and antecedent soil moisture. Perennials FC follow wet-dry multi-year regime shifts, while evergreen is completely decoupled from short term changes in water availability. Trend analysis suggests that different processes operate at the local scale. Regionally, evergreen cover increased while perennials and annuals cover decreased. Subsequently, urban land cover was compared with its surrounding desert. A distinct signal of rain use efficiency and aridity index was documented from remote sensing and a soil-water-balance model. It was estimated that a total of 295 mm of water input is needed to sustain current greenness. Finally, an energy balance model was developed to spatio-temporally estimate evapotranspiration (ET) as a proxy for water consumption, and evaluate land use/land cover types in response to drought. Agricultural fields show an average ET of 9.3 mm/day with no significant difference between drought and wet conditions, implying similar level of water usage regardless of climatic conditions. Xeric neighborhoods show significant variability between dry and wet conditions, while mesic neighborhoods retain high ET of 400-500 mm during drought due to irrigation. Considering the potentially limited water availability, land use/land cover changes due to population increases, and the threat of a warming and drying climate, maintaining large water-consuming, irrigated landscapes challenges sustainable practices of water conservation and the need to provide amenities of this desert area for enhancing quality of life.

The characteristics of the wintertime 500hPa height surface, the level of non-divergence and used for identifying/observing synoptic-scale features (ridges and troughs), and their impact on precipitation are of significance to forecasters, natural resource managers and planners across the southwestern United States. For this study, I evaluated the location of the 500hPa mean Pacific ridge axis over the winter for the period of 1948/49 to 2011/12 and derived the mean ridge axis in terms of location (longitude) and intensity (geopotential meters) from the NCEP/NCAR Reanalysis dataset. After deriving a mean ridge axis climatology and analyzing its behavior over time, I correlated mean location and intensity values to observed wintertime precipitation in select U.S. Climate Divisions in Arizona, Colorado, Nevada, Utah and New Mexico. This resulted in two findings. First specific to the 500hPa ridge behavior, the ridge has been moving eastward and also has been intensifying through time. Second, results involving correlation tests between mean ridge location and intensity indicate precipitation across the selected Southwest Climate Divisions are strongly related to mean ridge intensity slightly more than ridge location. The relationships between mean ridge axis and observed precipitation also are negative, indicating an increase of one of the ridge parameters (i.e. continued eastward movement or intensification) lead to drier winter seasons across the Southwest. Increased understanding of relationships between upper-level ridging and observed wintertime precipitation aids in natural resource planning for an already arid region that relies heavily on winter precipitation.

This dissertation research investigates both spatial and temporal aspects of Bronze Age land use and land cover in the Eastern Mediterranean using botanical macrofossils of charcoal and charred seeds as sources of proxy data. Comparisons through time and over space using seed and charcoal densities, seed to charcoal ratios, and seed and charcoal identifications provide a comprehensive view of island vs. mainland vegetative trajectories through the critical 1000 year time period from 2500 BC to 1500 BC of both climatic fluctuation and significant anthropogenic forces. This research focuses particularly on the Mediterranean island of Cyprus during this crucial interface of climatic and human impacts on the landscape. Macrobotanical data often are interpreted locally in reference to a specific site, whereas this research draws spatial comparisons between contemporaneous archaeological sites as well as temporal comparisons between non-contemporaneous sites. This larger perspective is particularly crucial on Cyprus, where field scientists commonly assume that botanical macrofossils are poorly preserved, thus unnecessarily limiting their use as an interpretive proxy. These data reveal very minor anthropogenic landscape changes on the island of Cyprus compared to those associated with contemporaneous mainland sites. These data also reveal that climatic forces influenced land use decisions on the mainland sites, and provides crucial evidence pertaining to the rise of early anthropogenic landscapes and urbanized civilization.

Accurate characterization of forest canopy cover from satellite imagery hinges on the development of a model that considers the level of detail achieved by field methods. With the improved precision of both optical sensors and various spatial techniques, models built to extract forest structure attributes have become increasingly robust, yet many still fail to address some of the most important characteristics of a forest stand's intricate make-up. The objective of this study, therefore, was to address canopy cover from the ground, up. To assess canopy cover in the field, a vertical densitometer was used to acquire a total of 2,160 percent-cover readings from 30 randomly located triangular plots within a 6.94 km2 study area in the central highlands of the Bradshaw Ranger District, Prescott National Forest, Arizona. Categorized by species with the largest overall percentage of cover observations (Pinus ponderosa, Populus tremuloides, and Quercus gambelii), three datasets were created to assess the predictability of coniferous, deciduous, and mixed (coniferous and deciduous) canopies. Landsat-TM 5 imagery was processed using six spectral enhancement algorithms (PCA, TCT, NDVI, EVI, RVI, SAVI) and three local windows (3x3, 5x5, 7x7) to extract and assess the various ways in which these data were expressed in the imagery, and from those expressions, develop a model that predicted percent-cover for the entire study area. Generally, modeled cover estimates exceeded actual cover, over predicting percent-cover by a margin of 9-13%. Models predicted percent-cover more accurately when treated with a 3x3 local window than those treated with 5x5 and 7x7 local windows. In addition, the performance of models defined by the principal components of three vegetation indices (NDVI, EVI, RVI) were superior to those defined by the principal components of all four (NDVI, EVI, RVI, SAVI), as well as the principal and tasseled cap components of all multispectral bands (bands 123457). Models designed to predict mixed and coniferous percent-cover were more accurate than deciduous models.

I present the results of studies from two historically separate fields of research: heat related illness and human thermal comfort adaptation. My research objectives were: (a) to analyze the relationships between climate and heat related morbidity in Phoenix, Arizona and Chicago, Illinois; (b) explore possible linkages of human thermal comfort adaptation to heat-related illness; and (c) show possible benefits of collaboration between the two fields of research. Previous climate and mortality studies discovered regional patterns in summertime mortality in North America: lower in hot, southern cities compared to more temperate cities. I examined heat related emergency (911) dispatches from these two geographically and climatically different cities. I analyzed with local weather conditions with 911 dispatches identified by responders as "heat" related from 2001 to 2006 in Phoenix and 2003 through 2006 in Chicago. Both cities experienced a rapid rise in heat-related dispatches with increasing temperature and heat index, but at higher thresholds in Phoenix. Overall, Phoenix had almost two and half times more heat-related dispatches than Chicago. However, Phoenix did not experience the large spikes of heat-related dispatches that occurred in Chicago. These findings suggest a resilience to heat-related illness that may be linked to acclimatization in Phoenix. I also present results from a survey based outdoor human thermal comfort field study in Phoenix to assess levels of local acclimatization. Previous research in outdoor human thermal comfort in hot humid and temperate climates used similar survey-based methodologies and found higher levels of thermal comfort (adaptation to heat) that in warmer climates than in cooler climates. The study presented in this dissertation found outdoor thermal comfort thresholds and heat tolerance levels in Phoenix were higher than previous studies from temperate climates more similar to Chicago. These differences were then compared to the differences in weather conditions associated with heat-related dispatches. The higher comfort thresholds in Phoenix were similar in scale to the climate differences associated with the upsurge in heat-related dispatches in Phoenix and Chicago. This suggests a link between heat related illness and acclimatization, and illustrates potential for collaboration in research between the two fields.

Isentropic analysis is a type of analysis that is based on using the concept of potential temperatures, the adiabatically established temperature at 1000 hPa. In the 1930s and 1940s this type of analysis proved to be valuable in indicating areas of increased moisture content and locations experiencing flow up or down adiabatic surfaces. However, in the early 1950s, this type of analysis faded out of use and not until the twenty-first century have some researchers started once again to examine the usefulness of isentropic analysis. One aspect in which isentropic analysis could be practical, based on prior research, is in severe weather situations, due to its ability to easily show adiabatic motion and moisture. As a result, I analyzed monthly climatological isentropic surfaces to identify distinct patterns associated with tornado occurrences for specific regions and months across the contiguous United States. I collected tornado reports from 1974 through 2009 to create tornado regions for each month across the contiguous United States and corresponding upper air data for the same time period. I then separated these upper air data into tornado and non-tornado days for specific regions and conducted synoptic and statistical analyses to establish differences between the two. Finally, I compared those results with analyses of individual case studies for each defined region using independent data from 2009 through 2010. On tornado days distinct patterns can be identified on the isentropic surface: (1) the average isentropic surface lowered on tornado days indicating a trough across the region, (2) a corresponding increase in moisture content occurred across the tornado region, and (3) wind shifted in such a manner to produce flow up the isentropic trough indicating uplift. When comparing the climatological results with the case studies, the isentropic pattern for the case studies in general was more pronounced compared to the climatological pattern; however, this would be expected as when creating the average the pattern/conditions will be smoothed. These findings begin to bridge the large gap in literature, show the usefulness of isentropic analysis in monthly and daily use and serve as catalysts to create a finer resolution database in isentropic coordinates.

Metropolitan Phoenix, Arizona, is one of the most rapidly urbanizing areas in the U.S., which has resulted in an urban heat island (UHI) of substantial size and intensity. Several detrimental biophysical and social impacts arising from the large UHI has posed, and continues to pose, a challenge to stakeholders actively engaging in discussion and policy formulation for a sustainable desert city. There is a need to mitigate some of its detrimental effects through sustainable methods, such as through the application of low-water, desert-adapted low-water use trees within residential yards (i.e. urban xeriscaping). This has the potential to sustainably reduce urban temperatures and outdoor thermal discomfort in Phoenix, but evaluating its effectiveness has not been widely researched in this city or elsewhere. Hence, this dissertation first evaluated peer-reviewed literature on UHI research within metropolitan Phoenix and discerned several major themes and factors that drove existing research trajectories. Subsequently, the nocturnal cooling influence of an urban green-space was examined through direct observations and simulations from a microscale climate model (ENVI-Met 3.1) with an improved vegetation parameterization scheme. A distinct park cool island (PCI) of 0.7-3.6 °C was documented from traverse and model data with larger magnitudes closer to the surface. A key factor in the spatial expansion of PCI was advection of cooler air towards adjacent urban surfaces, especially at 0-1 m heights. Modeled results also possessed varying but reasonable accuracy in simulating temperature data, although some systematic errors remained. Finally, ENVI-Met generated xeriscaping scenarios in two residential areas with different surface vegetation cover (mesic vs. xeric), and examined resulting impacts on near-surface temperatures and outdoor thermal comfort. Desert-adapted low-water use shade trees may have strong UHI mitigation potential in xeric residential areas, with greater cooling occurring at (i.) microscales (~2.5 °C) vs. local-scales (~1.1 °C), and during (ii.) nocturnal (0500 h) vs. daytime periods (1700 h) under high xeriscaping scenarios. Conversely, net warming from increased xeriscaping occurred over mesic residential neighborhoods over all spatial scales and temporal periods. These varying results therefore must be considered by stakeholders when considering residential xeriscaping as a UHI mitigation method.