Asphalt binder is a complex viscoelastic hydrocarbon, whose performance depends upon interaction between its physical and chemical properties, both of which are equally important to the successful understanding of the material. Researchers have proposed various models linking linear viscoelastic (LVE) and microstructural parameters. However, none of these parameters provide insight into the relationship in the non- linear viscoelastic NLVE domain. The main goals of this dissertation are two fold. The first goal is to utilize the technique of Laser Desorption Mass Spectroscopy (LDMS) to relate the molecular structure of asphalt binders to its viscoelastic properties. The second goal of the study is to utilize different NLVE characterization tools and analysis procedures to get a clear understanding of the NLVE behavior of the asphalt binders. The goals of the study are divided into four objectives; 1) Performing the LDMS test on asphalt binder to develop at the molecular weight distributions for different asphalts, 2) Characterizing LVE properties of Arizona asphalt binders, 3) Development of relationship between molecular structure and linear viscoelasticity, 4) Understanding NLVE behavior of asphalt binders through three different characterization methods and analysis techniques.

In this research effort, a promising physico-chemical relationship is developed between number average molecular weight and width of relaxation spectrum by utilizing the data from LVE characterization and the molecular weight distribution from LDMS. The relationship states that as the molecular weight of asphalt binders increase, they require more time to relax the developed stresses. Also, NLVE characterization was carried out at intermediate and high temperatures using three different tests, time sweep fatigue test, repeated stress/strain sweep test and Multiple Stress Creep and Recovery (MSCR) test. For the intermediate temperature fatigue tests, damage characterization was conducted by applying the S-VECD model and it was found that aged binders possess greater fatigue resistance than unaged binders. Using the high temperature LAOS tests, distortion was observed in the stress-strain relationships and the data was analyzed using a Fourier transform based tool called MITlaos, which deconvolves stress strain data into harmonic constituents and aids in identification of non-linearity by detecting higher order harmonics. Using the peak intensities observed at higher harmonic orders, non-linearity was quantified through a parameter termed as “Q”, which in future applications can be used to relate to asphalt chemical parameters. Finally, the last NLVE characterization carried out was the MSCR test, where the focus was on the scrutiny of the Jnrdiff parameter. It was found that Jnrdiff is not a capable parameter to represent the stress-sensitivity of asphalt binders. The developed alternative parameter Jnrslope does a better job of not only being a representative parameter of stress sensitivity but also for temperature sensitivity.

Road networks are valuable assets that deteriorate over time and need to be preserved to an acceptable service level. Pavement management systems and pavement condition assessment have been implemented widely to routinely evaluate the condition of the road network, and to make recommendations for maintenance and rehabilitation in due time and manner. The problem with current practices is that pavement evaluation requires qualified raters to carry out manual pavement condition surveys, which can be labor intensive and time consuming. Advances in computing capabilities, image processing and sensing technologies has permitted the development of vehicles equipped with such technologies to assess pavement condition. The problem with this is that the equipment is costly, and not all agencies can afford to purchase it. Recent researchers have developed smartphone applications to address this data collection problem, but only works in a restricted set up, or calibration is recommended. This dissertation developed a simple method to continually and accurately quantify pavement condition of an entire road network by using technologies already embedded in new cars, smart phones, and by randomly collecting data from a population of road users. The method includes the development of a Ride Quality Index (RQI), and a methodology for analyzing the data from multi-factor uncertainty. It also derived a methodology to use the collected data through smartphone sensing into a pavement management system. The proposed methodology was validated with field studies, and the use of Monte Carlo method to estimate RQI from different longitudinal profiles. The study suggested RQI thresholds for different road settings, and a minimum samples required for the analysis. The implementation of this approach could help agencies to continually monitor the road network condition at a minimal cost, thus saving millions of dollars compared to traditional condition surveys. This approach also has the potential to reliably assess pavement ride quality for very large networks in matter of days.

Pavement management systems and performance prediction modeling tools are essential for maintaining an efficient and cost effective roadway network. One indicator of pavement performance is the International Roughness Index (IRI), which is a measure of ride quality and also impacts road safety. Many transportation agencies use IRI to allocate annual maintenance and rehabilitation strategies to their road network.

The objective of the work in this study was to develop a methodology to evaluate and predict pavement roughness over the pavement service life. Unlike previous studies, a unique aspect of this work was the use of non-linear mathematical function, sigmoidal growth function, to model the IRI data and provide agencies with the information needed for decision making in asset management and funding allocation. The analysis included data from two major databases (case studies): Long Term Pavement Performance (LTPP) and the Minnesota Department of Transportation MnROAD research program. Each case study analyzed periodic IRI measurements, which were used to develop the sigmoidal models.

The analysis aimed to demonstrate several concepts; that the LTPP and MnROAD roughness data could be represented using the sigmoidal growth function, that periodic IRI measurements collected for road sections with similar characteristics could be processed to develop an IRI curve representing the pavement deterioration for this group, and that pavement deterioration using historical IRI data can provide insight on traffic loading, material, and climate effects. The results of the two case studies concluded that in general, pavement sections without drainage systems, narrower lanes, higher traffic, or measured in the outermost lane were observed to have more rapid deterioration trends than their counterparts.

Overall, this study demonstrated that the sigmoidal growth function is a viable option for roughness deterioration modeling. This research not only to demonstrated how historical roughness can be modeled, but also how the same framework could be applied to other measures of pavement performance which deteriorate in a similar manner, including distress severity, present serviceability rating, and friction loss. These sigmoidal models are regarded to provide better understanding of particular pavement network deterioration, which in turn can provide value in asset management and resource allocation planning.