Isotopic investigations of meteoritic materials: from earliest-formed solids to planetary bodies

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Description
The beginning of our Solar System, including events such as the formation of the first solids as well as the accretion and differentiation of planetary bodies, is recorded in meteoritic material. This record can be deciphered using petrographic, geochemical and

The beginning of our Solar System, including events such as the formation of the first solids as well as the accretion and differentiation of planetary bodies, is recorded in meteoritic material. This record can be deciphered using petrographic, geochemical and isotopic investigations of different classes of meteorites and their components. In this dissertation, I have investigated a variety of isotope systematics in chondritic and achondritic meteorites to understand processes that have shaped our Solar System. Specifically, the investigations conducted here are in two main areas: 1) Hydrogen isotope systematics in a meteorite representing the freshest known sample of the martian crust, and 2) Isotopic studies (specifically relating to high resolution chronology, nucleosynthetic anomalies and mass-dependent fractionations) in calcium-aluminum-rich inclusions, which are thought to be the earliest-formed solids in the Solar System. Chapter 1 of this dissertation presents a review of the hydrogen isotopic compositions of various planetary bodies and reservoirs in the Solar System, which could serve as tracers for the volatile sources. Chapter 2 focuses on an investigation of the hydrogen isotopic systematics in the freshest martian meteorite fall, Tissint, using the Cameca IMS-6f secondary ion mass spectrometer (SIMS). These first two chapters comprise the first part of this dissertation. The second part is comprised of chapters 3 through 6 and is focused on isotopic analyses of Calcium-Aluminum-rich Inclusions (CAIs). Chapter 3 is a review of CAIs, which record some of the earliest processes that occurred in the solar nebula. Chapter 4 presents the results of an investigation of the 26Al-26Mg short-lived chronometer (half-life ~0.72 Ma) in two CAIs and their Wark-Lovering (WL) rims from a CV3 carbonaceous chondrite using the Cameca NanoSIMS 50L. Chapter 5 is focused on the results of a study of the Zr isotope compositions of a suite of 15 CAIs from different carbonaceous chondrites using multicollector inductively coupled plasma mass spectrometry (MC-ICPMS), in order to identify nucleosynthetic anomalies in the CAI-forming region. Chapter 6 focuses on the mass-dependent Mg isotopic compositions measured in 11 CAIs from the Allende CV3 carbonaceous chondrite using MC-ICPMS, to evaluate effects of thermal processing on CAIs.
Date Created
2016
Agent

Modeling the interior of Haumea

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Description
The Kuiper Belt Object Haumea is one of the most fascinating objects in the solar system. Spectral reflectance observations reveal a surface of almost pure water ice, yet it has a mass of 4.006 × 1021 kg, measured from

The Kuiper Belt Object Haumea is one of the most fascinating objects in the solar system. Spectral reflectance observations reveal a surface of almost pure water ice, yet it has a mass of 4.006 × 1021 kg, measured from orbits of its moons, along with an inferred mean radius of 715 km, and these imply a mean density of around 2600 kg m−3. Thus the surface ice must be a veneer over a rocky core. This model is supported by observations of Haumea's light curve, which shows large photometric variations over an anomalously rapid 3.9154-hour rotational period. Haumea's surface composition is uniform, therefore the light curve must be due to a varying area presented to the observer, implying that Haumea has an oblong, ellipsoidal shape. If Haumea's rotation axis is normal to our line of sight, and Haumea reflects with a lunar-like scattering function, then its axis ratios are p = b/a = 0.80 (in the equatorial cross section) and q = c/a = 0.52 (in the polar cross section). In this work, I assume that Haumea is in hydrostatic equilibrium, and I model it as a two-phase ellipsoid with an ice mantle and a rocky core. I model the core assuming it has a given density in the range between 2700–3300 kg m−3 with axis ratios that are free to vary. The metric which my code uses calculates the angle between the gravity vector and the surface normal, then averages this over both the outer surface and the core-mantle boundary. When this fit angle is minimized, it allows an interpretation of the size and shape of the core, as well as the thickness of the ice mantle. Results of my calculations show that Haumea's most likely core density is 2700–2800 kg m−3, with ice thicknesses anywhere from 12–32 km over the poles and as thin as 4–18 km over the equator.
Date Created
2015
Agent

Prerequisites for Explosive Cryovolcanism on Dwarf Planet-Class Kuiper Belt Objects

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Description

Explosive extrusion of cold material from the interior of icy bodies, or cryovolcanism, has been observed on Enceladus and, perhaps, Europa, Triton, and Ceres. It may explain the observed evidence for a young surface on Charon (Pluto’s surface is masked

Explosive extrusion of cold material from the interior of icy bodies, or cryovolcanism, has been observed on Enceladus and, perhaps, Europa, Triton, and Ceres. It may explain the observed evidence for a young surface on Charon (Pluto’s surface is masked by frosts). Here, we evaluate prerequisites for cryovolcanism on dwarf planet-class Kuiper belt objects (KBOs). We first review the likely spatial and temporal extent of subsurface liquid, proposed mechanisms to overcome the negative buoyancy of liquid water in ice, and the volatile inventory of KBOs. We then present a new geochemical equilibrium model for volatile exsolution and its ability to drive upward crack propagation. This novel approach bridges geophysics and geochemistry, and extends geochemical modeling to the seldom-explored realm of liquid water at subzero temperatures. We show that carbon monoxide (CO) is a key volatile for gas-driven fluid ascent; whereas CO2 and sulfur gases only play a minor role. N2, CH4, and H2 exsolution may also drive explosive cryovolcanism if hydrothermal activity produces these species in large amounts (a few percent with respect to water). Another important control on crack propagation is the internal structure: a hydrated core makes explosive cryovolcanism easier, but an undifferentiated crust does not. We briefly discuss other controls on ascent such as fluid freezing on crack walls, and outline theoretical advances necessary to better understand cryovolcanic processes. Finally, we make testable predictions for the 2015 New Horizons flyby of the Pluto-Charon system.

Date Created
2015-01-15
Agent

External Photoevaporation of the Solar Nebula: Jupiter's Noble Gas Enrichments

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Description

We present a model explaining the elemental enrichments in Jupiter's atmosphere, particularly the noble gases Ar, Kr, and Xe. While He, Ne, and O are depleted, seven other elements show similar enrichments (~3 times solar, relative to H). Being volatile,

We present a model explaining the elemental enrichments in Jupiter's atmosphere, particularly the noble gases Ar, Kr, and Xe. While He, Ne, and O are depleted, seven other elements show similar enrichments (~3 times solar, relative to H). Being volatile, Ar is difficult to fractionate from H2. We argue that external photoevaporation by far-ultraviolet (FUV) radiation from nearby massive stars removed H2, He, and Ne from the solar nebula, but Ar and other species were retained because photoevaporation occurred at large heliocentric distances where temperatures were cold enough (lesssim 30 K) to trap them in amorphous water ice. As the solar nebula lost H, it became relatively and uniformly enriched in other species. Our model improves on the similar model of Guillot & Hueso. We recognize that cold temperatures alone do not trap volatiles; continuous water vapor production is also necessary. We demonstrate that FUV fluxes that photoevaporated the disk generated sufficient water vapor in regions [< over ~]30 K to trap gas-phase species in amorphous water ice in solar proportions. We find more efficient chemical fractionation in the outer disk: whereas the model of Guillot & Hueso predicts a factor of three enrichment when only <2% of the disk mass remains, we find the same enrichments when 30% of the disk mass remains. Finally, we predict the presence of ~0.1 M of water vapor in the outer solar nebula and protoplanetary disks in H II regions.

Date Created
2015-01-01
Agent

Astrobiological Stoichiometry

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Description

Chemical composition affects virtually all aspects of astrobiology, from stellar astrophysics to molecular biology. We present a synopsis of the research results presented at the “Stellar Stoichiometry” Workshop Without Walls hosted at Arizona State University April 11–12, 2013, under the

Chemical composition affects virtually all aspects of astrobiology, from stellar astrophysics to molecular biology. We present a synopsis of the research results presented at the “Stellar Stoichiometry” Workshop Without Walls hosted at Arizona State University April 11–12, 2013, under the auspices of the NASA Astrobiology Institute. The results focus on the measurement of chemical abundances and the effects of composition on processes from stellar to planetary scales. Of particular interest were the scientific connections between processes in these normally disparate fields. Measuring the abundances of elements in stars and giant and terrestrial planets poses substantial difficulties in technique and interpretation. One of the motivations for this conference was the fact that determinations of the abundance of a given element in a single star by different groups can differ by more than their quoted errors.

The problems affecting the reliability of abundance estimations and their inherent limitations are discussed. When these problems are taken into consideration, self-consistent surveys of stellar abundances show that there is still substantial variation (factors of ∼2) in the ratios of common elements (e.g., C, O, Na, Al, Mg, Si, Ca) important in rock-forming minerals, atmospheres, and biology. We consider how abundance variations arise through injection of supernova nucleosynthesis products into star-forming material and through photoevaporation of protoplanetary disks. The effects of composition on stellar evolution are substantial, and coupled with planetary atmosphere models can result in predicted habitable zone extents that vary by many tens of percent. Variations in the bulk composition of planets can affect rates of radiogenic heating and substantially change the mineralogy of planetary interiors, affecting properties such as convection and energy transport.

Date Created
2014-07-01
Agent

Variability of elemental abundances in the local neighborhood and its effect on planetary systems

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Description
As the detection of planets become commonplace around our neighboring stars, scientists can now begin exploring their possible properties and habitability. Using statistical analysis I determine a true range of elemental compositions amongst local stars and how this variation could

As the detection of planets become commonplace around our neighboring stars, scientists can now begin exploring their possible properties and habitability. Using statistical analysis I determine a true range of elemental compositions amongst local stars and how this variation could affect possible planetary systems. Through calculating and analyzing the variation in elemental abundances of nearby stars, the actual range in stellar abundances can be determined using statistical methods. This research emphasizes the diversity of stellar elemental abundances and how that could affect the environment from which planets form. An intrinsic variation has been found to exist for almost all of the elements studied by most abundance-finding groups. Specifically, this research determines abundances for a set of 458 F, G, and K stars from spectroscopic planet hunting surveys for 27 elements, including: C, O, Na, Mg, Al, Si, S, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Mo, Ba, La, Ce, Nd, Eu, and Hf. Abundances of the elements in many known exosolar planet host stars are calculated for the purpose investigating new ways to visualize how stellar abundances could affect planetary systems, planetary formation, and mineralogy. I explore the Mg/Si and C/O ratios as well as place these abundances on ternary diagrams with Fe. Lastly, I emphasize the unusual stellar abundance of τ Ceti. τ Ceti is measured to have 5 planets of Super-Earth masses orbiting in near habitable zone distances. Spectroscopic analysis finds that the Mg/Si ratio is extremely high (~2) for this star, which could lead to alterations in planetary properties. τ Ceti's low metallicity and oxygen abundance account for a change in the location of the traditional habitable zone, which helps clarify a new definition of habitable planets.
Date Created
2014
Agent

Trans-Neptunian and exosolar satellites and dust: dynamics and surface effects

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Description
Solar system orbital dynamics can offer unique challenges. Impacts of interplanetary dust particles can significantly alter the surfaces of icy satellites and minor planets. Impact heating from these particles can anneal away radiation damage to the crystalline structure of surface

Solar system orbital dynamics can offer unique challenges. Impacts of interplanetary dust particles can significantly alter the surfaces of icy satellites and minor planets. Impact heating from these particles can anneal away radiation damage to the crystalline structure of surface water ice. This effect is enhanced by gravitational focusing for giant planet satellites. In addition, impacts of interplanetary dust particles on the small satellites of the Pluto system can eject into the system significant amounts of secondary intra-satellite dust. This dust is primarily swept up by Pluto and Charon, and could explain the observed albedo features on Pluto's surface. In addition to Pluto, a large fraction of trans-neptunian objects (TNOs) are binary or multiple systems. The mutual orbits of these TNO binaries can range from very wide (periods of several years) to near-contact systems (less than a day period). No single formation mechanism can explain this distribution. However, if the systems generally formed wide, a combination of solar and body tides (commonly called Kozai Cycles-Tidal Friction, KCTF) can cause most systems to tighten sufficiently to explain the observed distributions. This KCTF process can also be used to describe the orbital evolution of a terrestrial-class exoplanet after being captured as a satellite of a habitable-zone giant exoplanet. The resulting exomoon would be both potentially habitable and potenially detectable in the full Kepler data set.
Date Created
2013
Agent

Morphological perspectives on galaxy evolution since z̃1.5

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Description
Galaxies represent a fundamental catalyst in the ``lifecycle'' of matter in the Universe, and the study of galaxy assembly and evolution provides unique insight into the physical processes governing the transformation of matter from atoms to gas to stars. With

Galaxies represent a fundamental catalyst in the ``lifecycle'' of matter in the Universe, and the study of galaxy assembly and evolution provides unique insight into the physical processes governing the transformation of matter from atoms to gas to stars. With the Hubble Space Telescope, the astrophysical community is able to study the formation and evolution of galaxies, at an unrivaled spatial resolution, over more than 90% of cosmic time. Here, I present results from two complementary studies of galaxy evolution in the local and intermediate redshift Universe which used new and archival HST images. First, I use archival broad-band HST WFPC2 optical images of local (d<63 Mpc) Seyfert-type galaxies to test the observed correlation between visually-classified host galaxy dust morphology and AGN class. Using quantitative parameters for classifying galaxy morphology, I do not measure a strong correlation between the galaxy morphology and AGN class. This result could imply that the Unified Model of AGN provides a sufficient model for the observed diversity of AGN, but this result could also indicate the quantitative techniques are insufficient for characterizing the dust morphology of local galaxies. To address the latter, I develop a new automated method using an inverse unsharp masking technique coupled to Source Extractor to detect and measure dust morphology. I measure no strong trends with dust-morphology and AGN class using this method, and conclude that the Unified Model remains sufficient to explain the diversity of AGN. Second, I use new UV-optical-near IR broad-band images obtained with the HST WFC3 in the Early Release Science (ERS) program to study the evolution of massive, early-type galaxies. These galaxies were once considered to be ``red and dead'', as a class uniformly devoid of recent star formation, but observations of these galaxies in the local Universe at UV wavelengths have revealed a significant fraction (30%) of ETGs to have recently formed a small fraction (5-10%) of their stellar mass in young stars. I extend the study of recent star formation in ETGs to intermediate-redshift 0.35<1.5 with the ERS data. Comparing the mass fraction and age of young stellar populations identified in these ETGs from two-component SED analysis with the morphology of the ETG and the frequency of companions, I find that at this redshift many ETGs are likely to have experienced a minor burst of recent star formation. The mechanisms driving this recent star formation are varied, and evidence for both minor merger driven recent star formation as well as the evolution of transitioning ETGs is identified.
Date Created
2013
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