According to Our World in Data, the industry sector contributes approximately 5.2 percent of the world's greenhouse gas emissions in 2016 [1]. Of that percentage, the cement industry contributes approximately 3 percent, thus accounting for more than 57 percent of all greenhouse gas emissions within the industry sector. Industrial-scale heating that is powered by renewable energy sources has the potential to combat this issue. This paper aims to analyze and model the Reverse Brayton Cycle to be used as a heat pump in a novel cement production system. The Simple Reverse Brayton Cycle and its potential concerning performance indicators such as coefficient of performance and scalability are determined. A Regenerative Brayton cycle is modeled in MATLAB® programming in order to be optimized and compared to conventional processes that require higher temperatures. Traditional manufacturing methods are discussed. Furthermore, possible methods of improvement are explored to view its effect on performance and temperatures between stages within the cycle.

This study investigates the energy saving potential of high albedo roof coatings which are designed to reflect a large proportion of solar radiation compared to traditional roofing materials. Using EnergyPlus simulations, the efficacy of silicone, acrylic, and aluminum roof coatings is assessed across two prototype commercial buildings—a standalone retail (2,294 m2 or 24,692 ft2) and a strip-mall (2,090 m2 or 22,500 ft2)—located in four cities: Phoenix, Houston, Los Angeles, and Miami. The performance of reflective coatings was compared with respect to a black roof having a solar reflectance of 5% and a thermal emittance of 90%. A sensitivity analysis was done to assess the impact of solar reflectance and thermal emittance on the ability of roof coatings to reduce surface temperatures, a key factor behind energy savings. This factor plays a crucial role in all three heat transfer mechanisms: conduction, convection, and radiation. The rooftop surface temperature exhibits considerable variation depending on the solar reflectance and thermal emittance attributes of the roof. A contour plot between these properties reveals that high values of both result in reduced cooling needs and a heating penalty which is insignificant when compared with cooling savings for cooling-dominant climates like Phoenix where the cooling demand significantly outweighs the heating demand, yielding significant energy savings. Furthermore, the study also investigates the effects of reflective coatings on buildings that have photovoltaic solar panels installed on them. This includes exploring their impact on building HVAC loads, as well as the performance improvement due to the reduced temperatures beneath them.

Ethylene is one of the most widely used organic compounds worldwide with ever increasing demand. Almost all the industries currently producing ethylene globally use the method of steam cracking, which, though highly selective and cost effective, is energy intensive along with having a high carbon footprint. This study aims to analyze micro-scale partial oxidation of propane as a novel approach towards ethylene generation which is simpler, less energy consuming, operates at lower temperatures and causes minimum CO2 emission. The experimental study endeavors to maximize the ethylene production by investigating the effect of variables such as temperature, flow rate, equivalence ratio and reactor diameter. The micro-scale partial oxidation of propane is studied inside quartz tube reactors of 1 mm and 3 mm diameter at a temperature range of 800 to 900 oC, at varying flow rates of 10 to 100 sccm and equivalence ratios of 1 to 6. The study reveals ethylene yield has a strong dependence on all the above factors. However, the factors are not completely independent of each other. Adjusting certain factors and levels results in greater ethylene yields as high as 10%, but propane to ethylene conversion efficiency is approximately constant for most conditions. Low CO2 concentrations are also recorded for most of the factor and level combinations, indicating the potential to achieve lower CO2 yields compared to conventional approaches. The investigation indicates promise for application in the field of ethylene generation.

Energy storage technologies are essential to overcome the temporal variability in renewable energy. The primary aim of this thesis is to develop reactor solutions to better analyze the potential of thermochemical energy storage (TCES) using non-stoichiometric metal oxides, for the multi-day energy storage application. A TCES system consists of a reduction reactor and an insulated MOx storage bin. The reduction reactor heats (to ~ 1100 °C) and partially reduces the MOx, thereby adding sensible and chemical energy (i.e., charging it) under reduced pO2 environments (~10 Pa). Inert gas removes the oxygen generated during reduction. The storage bin holds the hot and partially reduced MOx (typically particles) until it is used in an energy recovery device (i.e., discharge). Irrespective of the reactor heat source (here electrical), or the particle-inert gas flows (here countercurrent), the thermal reduction temperature and inert gas (here N2) flow minimize when the process approaches reversibility, i.e., operates near equilibrium. This study specifically focuses on developing a reduction reactor based on the theoretical considerations for approaching reversibility along the reaction path. The proposed Zigzag flow reactor (ZFR) is capable of thermally reducing CAM28 particles at temperatures ~ 1000 °C under an O2 partial pressure ~ 10 Pa. The associated analytical and numerical models analyze the reaction equilibrium under a real (discrete) reaction path and the mass transfer kinetic conditions necessary to approach equilibrium. The discrete equilibrium model minimizes the exergy destroyed in a practical reactor and identifies methods of maximizing the energy storage density () and the exergetic efficiency. The mass transfer model analyzes the O2 N2 concentration boundary layers to recommend sizing considerations to maximize the reactor power density. Two functional ZFR prototypes, the -ZFR and the -ZFR, establish the proof of concept and achieved a reduction extent, Δδ = 0.071 with CAM28 at T~950 °C and pO2 = 10 Pa, 7x higher than a previous attempt in the literature. The -ZFR consistently achieved  > 100 Wh/kg during >10 h. runtime and the -ZFR displayed an improved  = 130 Wh/kg during >5 h. operation with CAM28. A techno-economic model of a grid-scale ZFR with an associated storage bin analyzes the cost of scaling the ZFR for grid energy storage requirements. The scaled ZFR capital costs contribute < 1% to the levelized cost of thermochemical energy storage, which ranges from 5-20 ¢/kWh depending on the storage temperature and storage duration.

Failures in the cold chain, the system of refrigerated storage and transport that provides fresh produce or other essentials to be maintained at desired temperatures and environmental conditions, lead to food and energy waste. The mini container (MC) concept is introduced as an alternative to conventional refrigerated trucks (“reefers”), particularly for small growers. The energy consumption and corresponding GHG emissions for transporting tomatoes in two cities representing contrasting climates is analyzed for conventional reefers and the proposed mini containers. The results show that, for partial reefer loads, using the MCs reduces energy consumption and GHG emissions. The transient behavior of the vapor compression refrigeration cycle is analyzed by considering each component as a “lumped” system, and the resulting sub-models are solved using the Runge Kutta 4th-order method in a MATLAB code at hot and cold ambient temperatures. The time needed to reach steady state temperatures and the temperature values are determined. The maximum required compressor work in the transient phase and at steady state are computed, and as expected, as the ambient temperature increases, both values increase. Finally, the average coefficient of performance (COP) is determined for varying heat transfer coefficient values for the condenser and for the evaporator. The results show that the average COP increases as heat transfer coefficient values for the condenser and the evaporator increase. Starting the system from rest has an adverse effect on the COP due to the higher compressor load needed to change the temperature of the condenser and the evaporator. Finally, the impact on COP is analyzed by redirecting a fraction of the cold exhaust air to provide supplemental cooling of the condenser. It is noted that cooling the condenser improves the system's performance better than cooling the fresh air at 0% of returned air to the system.To sum up, the dissertation shows that the comparison between the conventional reefer and the MC illustrates the promising advantages of the MC, then a transient analysis is developed for deeply understanding the behaviors of the system component parameters, which leads finally to improvements in the system to enhance its performance.

Sweat evaporation is fundamental to human thermoregulation, yet our knowledge of the microscale sweat droplet evaporation dynamics is very limited. To study sweat droplet evaporation, a reliable way to measure sweat evaporation rate from skin and simultaneously image the droplet dynamics through midwave infrared thermography (MWIR) or optical coherence tomography (OCT) is required. Ventilated capsule is a common device employed for measuring sweat evaporation rates in physiological studies. However, existing designs of ventilated capsules with cylindrical flow chambers create unrealistic flow conditions that include flow separation and swirling. To address this problem, this thesis introduces a ventilated capsule with rectangular sweat evaporation area preceded by a diffuser section with geometry based on wind tunnel design guidelines. To allow for OCT or MWIR imaging, a provision to install an acrylic or a sapphire window directly over the exposed skin surface being measured is incorporated in the design. In addition to the capsule, a simplified artificial sweating surface that can supply water in a filmwise, single or multiple droplet form was developed. The performance of the capsule is demonstrated using the artificial sweating surface along with example MWIR imaging.

The conversion of H2S enables the recycling of a waste gas into a potential source of hydrogen at a lower thermodynamic energy cost as compared to water splitting. However, studies on the photocatalytic decomposition of H2S focus on traditional deployment of catalyst materials to facilitate this conversion, and operation only when a light source is available. In this study, the efficacy of Direct Ink Written (DIW) luminous structures for H2S conversion has been investigated, with the primary objective of sustaining H2S conversion when a light source has been terminated. Additionally, as a secondary objective, improving light distribution within monoliths for photocatalytic applications is desired. The intrinsic illumination of the 3D printed monoliths developed in this work could serve as an alternative to monolith systems that employ light transmitting fiber optic cables that have been previously proposed to improve light distribution in photocatalytic systems. The results that were obtained demonstrate that H2S favorable adsorbents, a wavelength compatible long afterglow phosphor, and a photocatalyst can form viscoelastic inks that are printable into DIW luminous monolithic contactors. Additionally, rheological, optical and porosity analyses conducted, provide design guidelines for future studies seeking to develop DIW luminous monoliths from compatible catalyst-phosphor pairs. The monoliths that were developed demonstrate not only improved conversion when exposed to light, but more significantly, extended H2S conversion from the afterglow of the monoliths when an external light source was removed. Lastly, considering growing interests in attaining a global circular economy, the techno-economic feasibility of a H2S-CO2 co-utilization plant leveraging hydrogen from H2S photocatalysis as a feed source for a downstream CO2 methanation plant has been assessed. The work provides preliminary information to guide future chemical kinetic design characteristics that are important to strive for if using H2S as a source of hydrogen in a CO2 methanation facility.

Solid Oxide Fuel Cells (SOFCs) generate electricity using only hydrogen and oxygen and they form H2O as the only byproduct, giving them the potential to significantly reduce carbon emissions and the impacts of global warming. In order to meet the global power demands today, SOFCs need to significantly increase their power density and improve robustness in startup and cycling operations. This study explores the impact of decreasing the anode thickness to improve the mass transport of the fuel through the anode of a micro-tubular (mT) SOFC because few studies have reported the correlation between the two. Decreasing the thickness decreases the chance for concentration overpotential which is caused by not enough of the reactants being able to reach the reaction site while products are not able to be removed quickly enough. Experiments were performed in a split tube furnace heated to 750°C with nickel-yttria stabilized zirconia (Ni-YSZ) supported cells. Pure hydrogen was supplied to the cell at rates of 10, 20, 30, and 40 mL/min while the cathode was supplied air from the environment. The cell's performance was studied using the current-voltage method to generate polarization curves and electrochemical impedance spectroscopy to create Bode and Nyquist plots. The results from the electrochemical impedance spectroscopy show a lower impedance for the frequencies pertaining to the gas diffusion in the anode for the thinner cells. This suggests that decreasing the anode thickness increases the mass transport of the gas. Additionally, through a distribution of relaxation times (DRT) analysis, the peaks vary between the two cell thicknesses at the frequencies pertaining to gas diffusion in anode-supported cells, implicating the decreased resistance created by thinning the anode layer.

This research aims to develop a single-phase immersion cooling system for CPU (Central Processing Unit) processors. To achieve this, a heat pipe with a dielectric liquid is designed to be used to cool the CPU, relying only on natural convection. A Tesla valve phenomenon is used to achieve the one-directional, recirculating system. A comparative study was conducted between two different single-phase dielectric fluids Mineral Oil and FC 3283 (Fluorocarbon), utilizing natural convection and Boussinesq correlations. ANSYS Fluent was used to conduct CFD (Computational Fluid Dynamics) analysis, demonstrating natural convection and recirculating flow in the heating direction. A comparison was made between the traditional cooling method of air and the developed immersion cooling system, with the results indicating that the system is capable of reducing the operating temperature of the CPU by 40 to 50 degrees Celsius, depending on the power consumption. The results of the experiment conducted showed that a processor cooled by Mineral oil would operate at 56 degrees Celsius, while a processor cooled by FC 3283 would operate at 47 degrees Celsius. By comparison, a processor cooled by the traditional air-cooled system would operate between 80 and 100 degrees Celsius. These results demonstrate that the Mineral oil and FC 3283 cooling systems are significantly more efficient than the traditional air-cooled system. This could prove to be a valuable asset in the development of more efficient cooling systems. Further research is necessary to evaluate the longevity, cost-effectiveness, and benefits of these systems in comparison to traditional air cooling

This study introduces a new outdoor accelerated testing method called “Field Accelerated Stress Testing (FAST)” for photovoltaic (PV) modules performed at two different climatic sites in Arizona (hot-dry) and Florida (hot-humid). FAST is a combined accelerated test methodology that simultaneously accounts for all the field-specific stresses and accelerates only key stresses, such as temperature, to forecast the failure modes by 2- 7 times in advance depending on the activation energy of the degradation mechanism (i.e., 10th year reliability issues can potentially be predicted in the 2nd year itself for an acceleration factor of 5). In this outdoor combined accelerated stress study, the temperatures of test modules were increased (by 16-19℃ compared to control modules) using thermal insulations on the back of the modules. All other conditions (ambient temperature, humidity, natural sunlight, wind speed, wind direction, and tilt angle) were left constant for both test modules (with back thermal insulation) and control modules (without thermal insulation). In this study, a total of sixteen 4-cell modules with two different construction types (glass/glass [GG] and glass/backsheet [GB]) and two different encapsulant types (ethylene vinyl acetate [EVA] and polyolefin elastomer [POE]), were investigated at both sites with eight modules at each site (four insulated and four non-insulated modules at each site). All the modules were extensively characterized before installation in the field and after field exposure over two years. The methods used for characterizing the devices included I-V (current-voltage curves), EL (electroluminescence), UVF (ultraviolet fluorescence), and reflectance. The key findings of this study are: i) the GG modules tend to operate at a higher temperature (1-3℃) than the GB modules at both sites of Arizona and Florida (a lower lifetime is expected for GG modules compared to GB modules); ii) the GG modules tend to experience a higher level of encapsulant discoloration and grid finger degradation than the GB modules at both sites (a higher level of the degradation rate is expected in GG modules compared to GB modules); and, iii) the EVA-based modules tend to have a higher level of discoloration and finger degradation compared to the POE-based modules at both sites.