Mars at No Charge: Active Neutron Spectroscopy for Magma Evolution, Clay Hydration, and Amorphous Composition in Gale Crater, Mars

Neutron spectroscopy is used to determine bulk water abundances in the near surface of planetary bodies. The Dynamic Albedo of Neutrons (DAN) instrument on the Mars Science Laboratory (MSL) rover, Curiosity, is able to determine the depth distribution of water and neutron absorbers in the top ~50 cm of the subsurface. In this dissertation, I focus on answering significant geologic questions by interpreting DAN results in the geologic context provided by other MSL and orbital datasets. This approach enabled me to investigate significant outstanding questions in Gale crater geology, with implications for the evolution and habitability of Mars.I mapped an extensive silicic volcaniclastic layer in the subsurface, the first identified and mapped on Mars. This layer served as a silica source for other silica-rich features. But unlike those features, this layer contains abundant rhyolitic glass, indicating an evolved volcanic origin. Similar material on Earth is produced by plate tectonics, so this layer has important implications for the evolution of Mars, which has no evidence of plate tectonics. One of the primary motivations for exploring Gale crater is a distinct clay mineral signature from orbital data of the Compact Reconnaissance Imaging Spectrometer at Mars (CRISM), which has also identified a corresponding hydration signature. I compared DAN and CRISM hydration results and found that CRISM hydration results are biased by the presence of regolith, indicating that this regolith is either more hydrated or has a different grain size texture than bedrock. Clay minerals are primary binding sites for organics on Earth, and most organic-mineral binding mechanisms involve either water or hydroxyl. This makes hydrated clays the most efficient hosts for organic preservation, but clays are normally dehydrated when measured by MSL. However, my DAN-derived water abundances are greater in the most clay-rich unit of Gale crater, suggesting that clay minerals may be hydrated in the subsurface. I developed a new amorphous component analysis method that simultaneously constrains clay mineral hydration and abundances of various hydrated amorphous phases. I found a strong correlation between “excess” water and smectites (expandable clay minerals), indicating that these clay minerals are hydrated in the subsurface.