Kinetic Analysis of O3 Decomposition over TiO2 photocatalyst for passive urban pollutant removal in Los Angeles

Ozone is a highly reactive compound that is harmful at very low concentrations as compared to other pollutants. One method of pollution control is the use of photocatalysis, specifically with titanium dioxide to induce ozone decomposition. An experiment was designed and executed in order to determine the rate of decomposition by coating concrete in 5% by weight titanium dioxide mixed with paint. The experiment was unsuccessful in inducing decomposition but gave important insight into the adsorptive properties of ozone over surfaces, particularly with bare concrete that had an adsorption of 22.51 ± 2.457 ppbv, which was much better than the coated samples. Further studies into the development of photocatalytic paint is needed in order to develop an effective urban ozone pollution control method to be implemented in major cities, particularly in the most polluted such as Los Angeles, California.